NOx Emissions from Cement Mfg - US Environmental Protection ...

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TABLE 4-3. (con.) Capacity Heat in NO x emissions Method and Location Kiln # Kiln type (tons/hr) Fuel burned MM Btu/ton (lb/ton clinker) date of data Reference Knoxville, TN 1 Preheater- 80 75% - Coal 3.6 7 CEM 82 Precalciner 12% - LWDF Jan-91 13% - SWDF 4-30
emission rates may thus be attributed to the difference in the energy consumption rates in these two types of kilns. The preheater type of kilns was reported to produce NO x emissions in the range of 2.5 to 11.7 lb NO /ton of clinker with x an average of 5.9 lb NO /ton of clinker. The highest values of x 8.1 and 11.7 were incidently found in gas burning kilns. As expected, the energy consumption of preheater kilns was much lower, about 3.8 MM Btu/ton. In addition, combustion of a part of the fuel at a lower preheating temperature is expected to reduce the NO emissions as compared to burning all the fuel in x the hot kiln burning zone. These two factors account for the lower NO emissions in preheater kilns as compared to long wet or x dry kilns. The precalciner kilns produced the least NO emissions ranging x <strong>from</strong> 0.9 to 7.0 with an average of 3.4 lb NO /ton of clinker. x These kilns were also the most energy efficient with an average energy consumption of 3.3 MM Btu/ton of clinker. In precalciner kilns, the proportion of the fuel burned at the calcining temperature is much greater as compared to the preheater type kilns leading to lower NO emissions. x The literature data indicate substantial spread in the reported NO emissions with significant overlap for different x kiln types. The four different cement kiln types, however, do appear to have different levels of NO emissions and different x characteristics influencing NO formation. The emission factors x based on the information obtained during this study will be used 4-31
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EPA-453/R-94-004 ALTERNATIVE CONTRO
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ALTERNATIVE CONTROL TECHNOLOGY DOCU
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Chapter Page 4.1 MECHANISMS OF NO F
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TABLE OF CONTENTS (con.) Chapter Pa
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LIST OF TABLES Number Page 2-1 UNCO
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CHAPTER 1 INTRODUCTION Congress, in
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CHAPTER 2 SUMMARY This chapter pres
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2.2 NO EMISSION CONTROL TECHNOLOGIE
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TABLE 2-2. ACHIEVABLE NO REDUCTIONS
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TABLE 2-4. CAPITAL AND ANNUAL COSTS
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TABLE 2-5. COST EFFECTIVENESS OF NO
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eductions ranged from 470 tons/year
Page 25 and 26: CHAPTER 3 INDUSTRY DESCRIPTION 3.1
Page 27 and 28: Type II. Moderate-heat-of-hardening
Page 29 and 30: 3 a TABLE 3-2. UNITED STATES CEMENT
Page 31 and 32: Figure 3-1. U.S. Portland cement pl
Page 33 and 34: Table 3-3. (con.) Rank Clinker 3 (1
Page 35 and 36: 5 cement processes: wet process and
Page 37 and 38: Figure 3-3. New technology in dry-p
Page 39 and 40: substantial levels of silica and al
Page 41 and 42: are achieved by clinker coolers of
Page 43 and 44: 126,000 to 963,000 tons/year with a
Page 45: such as crushing and grinding opera
Page 48 and 49: 4.1.1 Thermal NO Formation x Therma
Page 50 and 51: temperatures are on the order of 16
Page 52 and 53: 4-6
Page 54 and 55: expected to produce more fuel NO th
Page 56 and 57: introduce a large proportion of com
Page 58 and 59: will also mean a somewhat lower sec
Page 60 and 61: ILC systems: In these systems, the
Page 62 and 63: which indicates an average and the
Page 64 and 65: 4-18
Page 66 and 67: Uncontrolled NO x emissions Plant c
Page 68 and 69: from 2 to 9 lb/ton of clinker, and
Page 70 and 71: Capacity Heat in NO x emissions Met
Page 72 and 73: TABLE 4-3. (con.) Capacity Heat in
Page 74 and 75: TABLE 4-3. (con.) Capacity Heat in
Page 78 and 79: in estimating uncontrolled and cont
Page 80 and 81: 13. Letter from Sheridan, S.E., to
Page 82 and 83: 44. Chemecology Corporation Source.
Page 84 and 85: 73. Letter and attachments from Smi
Page 86 and 87: NO control approaches applicable to
Page 88 and 89: 5.1.2.2 Kiln Fuel Changing the prim
Page 90 and 91: oxygen content of the primary air m
Page 92 and 93: tend to recirculate hot combustion
Page 94 and 95: e about 15 to 38 percent depending
Page 96 and 97: combustion system shown in Figure 5
Page 98 and 99: 5-14
Page 100 and 101: Figure 5-3. Schematic of hazardous
Page 102 and 103: 5-18
Page 104 and 105: higher than typical cement kiln flu
Page 106 and 107: window is in the middle of a kiln.
Page 108 and 109: Figure 5-4. Application of the sele
Page 110 and 111: in Section 5.1.2 is usually difficu
Page 112 and 113: 5.4 REFERENCES 1. Helmuth, R.A., F.
Page 114 and 115: 25. Letter from Wax, J., Institute
Page 116 and 117: TABLE 6-1. CEMENT KILN MODEL PLANTS
Page 118 and 119: 6-4
Page 120 and 121: 6-6
Page 122 and 123: The total capital cost is the sum o
Page 124 and 125: TABLE 6-3. ANNUALIZED COST ELEMENTS
Page 126 and 127:
6-12
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6.1.3.7 Administrative Charges. The
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At this time only three installatio
Page 132 and 133:
6-18
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The annualized costs for low NOx bu
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No additional costs for utilities o
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20 percent PEC cost for contingenci
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TABLE 6-7. ANNUALIZED COSTS FOR RET
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6-28
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PEC for model plant 300,000 ' Heat
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TABLE 6-9. ANNUALIZED COSTS FOR MID
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6-34
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TABLE 6-10. CAPITAL COSTS FOR A URE
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TABLE 6-11. ANNUAL OPERATING COSTS
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6-40
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TABLE 6-12. CAPITAL COSTS FOR AN AM
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TABLE 6-13. ANNUAL OPERATING COSTS
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6-46
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costs range from $9.9 million for t
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The estimated annualized costs for
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6.3 COST EFFECTIVENESS OF NOx CONTR
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emoved. Cost effectiveness were det
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TABLE 6-17. COST EFFECTIVENESS OF R
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6-58
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TABLE 6-18. COST EFFECTIVENESS OF M
Page 176 and 177:
TABLE 6-19. COST EFFECTIVENESS OF U
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6.3.4 Selective Catalytic Reduction
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6-66
Page 182 and 183:
TABLE 6-21. COST EFFECTIVENESS OF S
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6-70
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11. Letter and attachments from Nov
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Tables 7-1 7-2
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TABLE 7-2. REDUCTION IN NO x EMISSI
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model plants described in Section 6
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temperature and excess air may be u
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NOxemissions will form. The heater
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equirement for the flue gas reheati
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