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The Chemistry of Powder and Explosives - Sciencemadness Dot Org

The Chemistry of Powder and Explosives - Sciencemadness Dot Org

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AMMONIUM PICRATE 167<br />

80° <strong>and</strong> 90° <strong>and</strong> are prepared by putting the materials together<br />

under water in wooden tanks <strong>and</strong> blowing in live steam. Th#<br />

water is sometimes acidulated with sulfuric acid to insure the<br />

removal <strong>of</strong> all metallic picrates. An explosive made by mixing<br />

88 parts <strong>of</strong> picric acid with 12 parts <strong>of</strong> melted paraffin or stearic<br />

acid, <strong>and</strong> then rolling <strong>and</strong> graining, gives a compact charge when<br />

loaded by compression. It is nearly as powerful <strong>and</strong> brisant<br />

as picric acid, <strong>and</strong> responds satisfactorily to the impulse<br />

<strong>of</strong> the detonator, but is distinctly less sensitive to mechanical<br />

shock.<br />

Ammonium Picrate<br />

Ammonium picrate is less sensitive to shock than picric acid. It<br />

is not easily detonated by fulminate, but is commonly used with a<br />

FIGURE 49. Commercial Sample <strong>of</strong> Ammonium Picrate (25X).<br />

booster <strong>of</strong> powdered <strong>and</strong> compressed picric acid or tetryl. <strong>The</strong><br />

pure substance occurs in two forms, a sta? form which is <strong>of</strong> a

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