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download pdf version of PhD book - Universiteit Utrecht

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4.5 Discussion<br />

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Figure 4.10: Calculated values <strong>of</strong> the core-scale detachment coefficient,<br />

kdet, c as a function <strong>of</strong> the local-scale distribution coefficient, k d ,<br />

and mean pore-water velocity. The circles are data points and the<br />

surface represents results <strong>of</strong> Equation (4.16) fitted to kdet c − k d − v data<br />

points.<br />

k c att = Kc D kc det = S k d<br />

This equation may be approximated by<br />

D 0.95<br />

mol v0.05<br />

(0.02 + 0.5k d )R 0.95 (4.18)<br />

k c att = S D 0<br />

0.5 R<br />

(4.19)<br />

which is the same as the equation derived through the averaging method by<br />

Rao<strong>of</strong> and Hassanizadeh [2010a].<br />

As mentioned above, Equations (4.16) and (4.18) were obtained based on results<br />

from a specific pore network. We have verified these equations by applying<br />

them to another pore network with the same pore-body size distribution as in<br />

Figure (4.2) but with a different mean pore-throat size, as well as a network<br />

with different pore-body size distribution and a mean pore-body diameter <strong>of</strong><br />

0.36 × 10 −3 m. Figures (4.11) and (4.12) show the results <strong>of</strong> the verification;<br />

plotted lines are obtained from Equation (4.16) for these networks while the<br />

circles indicate pore-network computations. It is evident that the agreement is<br />

excellent.<br />

Equations (4.16) and (4.18) show the upscaling relations for the core scale<br />

83

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