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download pdf version of PhD book - Universiteit Utrecht

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6. Dispersivity under Partially-Saturated Conditions<br />

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

r.<br />

Pe<br />

1<br />

0.8<br />

0.6<br />

04 0.4<br />

0.2<br />

0<br />

var L<br />

var M<br />

var H<br />

0 0.2 0.4 Sw 0.6 0.8 1<br />

Figure 6.8: The relation between fraction <strong>of</strong> percolating saturated pores and<br />

saturation shown for three networks.<br />

ate a “fast” flowing domain, since they are saturated and also connected to<br />

inlet boundary which imposes boundary pressure on these series <strong>of</strong> pores. The<br />

unsaturated pore system will create a “slow” flowing domain. The residence<br />

time <strong>of</strong> solute will be much higher in the unsaturated pore system compared<br />

to the saturated pore system, which could cause extra dispersion. It worth<br />

mentioning that, for a given pore network, the value <strong>of</strong> coefficient <strong>of</strong> variation<br />

for a fixed saturation is a constant irrespective <strong>of</strong> applied pressure gradients<br />

(different pore-water velocities). This is because, although the higher pressure<br />

gradient increases the velocities within pore throats and also increases the<br />

variance <strong>of</strong> velocities within different pore throats, the increase in variance is<br />

canceled out with the increase in the average velocity, and the coefficient <strong>of</strong><br />

variation remains constant. This is obviously not the case when the saturation<br />

changes, since saturation changes will change the distribution <strong>of</strong> the phase<br />

available to flow.<br />

6.5.2 Mobile-Immobile Model (MIM)<br />

Under unsaturated conditions, non-equilibrium effects may exist due to preferential<br />

flow paths. There are experimental studies which can not be properly<br />

described via the ADE model [Beven and Young, 1988]. Under such conditions,<br />

modified forms <strong>of</strong> ADE should be used to take into account the effects <strong>of</strong><br />

preferential flow or bypassing in the pore system. Drainage <strong>of</strong> pores will cause<br />

changes in velocity distributions and magnitudes <strong>of</strong> pore scale velocities. In<br />

particular, zones <strong>of</strong> low velocity or practically stagnant zones may be created.<br />

148

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