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Moose River Basin: geology and mineral potential - Geology Ontario

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Lignite <strong>and</strong> Industrial Mineral Resources<br />

greater amount of organic impurities than the white clays, are less likely to<br />

have been affected by post-depositional weathering than kaolinitic clays asso<br />

ciated with quartz s<strong>and</strong>. The latter kaolinitic clays may well be due entirely to<br />

post-depositional weathering of the feldspathic component of the s<strong>and</strong>s. Under<br />

these circumstances individual beds of kaolinitic clay may result from minor<br />

washing <strong>and</strong> transport at surface or they may be due to vertical migration of<br />

fine clay particles through the s<strong>and</strong> <strong>and</strong> concentration at certain levels. The<br />

latter process is believed to have been responsible for beds with 92 to 93 percent<br />

kaolinite in residual deposits in North Carolina (U.S. Bureau of Mines Bull.<br />

No.53,1913,p.l6).<br />

Silica S<strong>and</strong><br />

Weathering of rocks <strong>and</strong> transport of the weathered material leads to accu<br />

mulation of weathering-resistant particles. The accumulation may occur at the<br />

site of weathering or weathering-resistant particles may be washed away by<br />

rain or flood waters <strong>and</strong> selectively deposited downstream. If quartz is^the pre<br />

dominant weathering resistant <strong>mineral</strong> in the original rock, the resulting sedi<br />

ment is a nearly pure quartz s<strong>and</strong>. Quartz is a ubiquitous <strong>mineral</strong>. In granite<br />

the quartz content often ranges from 20-359fc (Hewitt 1972, p.57), <strong>and</strong> it is par<br />

ticularly abundant in rhyolites, granites, granite-gneisses <strong>and</strong> clastic sedi<br />

ments. Quartz, with formula SiO2 , hardness 7 (Moh's scale), <strong>and</strong> specific grav<br />

ity 2.65, lacks cleavage. Prolonged physical abrasion results in perfect<br />

rounding of the grains. Quartz is insoluble in acids except hydrofluoric acid. It<br />

is constant in composition <strong>and</strong>, by nature, of high purity.<br />

In source rocks quartz occurs in a wide range of grain sizes, from large bod<br />

ies measured in metres in pegmatites to the size of rock flour in the clay frac<br />

tion of sediments. Deposits of quartz s<strong>and</strong> are characterized by a specific grain<br />

size distribution corresponding to their origin. The effective grain size is occa<br />

sionally influenced by cementing of the s<strong>and</strong> grains. The cementation agent<br />

may be silica or carbonate. Silica cement permits the use of s<strong>and</strong>stone as a<br />

source of lump silica required for the manufacture of ferrosilicon.<br />

SILICA SAND - KAOLIN CLAY ASSOCIATION<br />

Unconsolidated quartz s<strong>and</strong>s associated with kaolinitic clay are frequently<br />

of high purity ^29c impurities). The weathering process responsible for kao<br />

linization has simultaneously depleted the deposit of iron, magnesium, calci<br />

um, <strong>and</strong> alkalies, particularly in areas where kaolinization is complete. The<br />

major remaining source of impurities is a residue of heavy <strong>mineral</strong>s, e.g. rutile,<br />

zircon, magnetite, staurolite. Heavier than quartz, some of these <strong>mineral</strong>s have<br />

been incorporated in lighter grains or failed to respond to gravity separation<br />

over the distance of transport from the source rock. This distance is characteris<br />

tically short for material in a quartz s<strong>and</strong> - kaolinitic clay association.<br />

Size sorting of quartz grains is also a function of the distance of transport.<br />

155

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