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Fundamental Organic Chemistry

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solvent Bp( O C) Useful for<br />

water 100<br />

Salts amides some<br />

carboxylic acids<br />

methanol 65 General use<br />

ethanol 78 General use<br />

acetone 56 General use<br />

ethylacetate 77 General use<br />

dichloromethane 40 General use<br />

Diethyl ether 35 General use<br />

Chloroform 61 General use<br />

toluene 111 Aromatic compound<br />

benzene 80 Aromatic compound<br />

Hexane(petroleum<br />

ether)<br />

69 hydrocarbons<br />

Table 1: Some common crystallization solvents<br />

Ideally, a compound to be crystallized should be soluble in the hot solvent,<br />

but insoluble in the cold solvent. When a proper solvent cannot be found, a<br />

chemist may use a solvent pair.<br />

13

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