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Fundamental Organic Chemistry

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ead. It provides a large surface area for vaporization and condensation of the<br />

liquid mixture.<br />

Ethanol is more volatile than water, since it has a lower boiling point<br />

(78 o C). The vapor rises up the fractionating column when the mixture is heated.<br />

Because ethanol is more volatile, the vapor contains more ethanol. The hot vapor<br />

condenses upon touching the cold glass beads. There is a continues rise of hot<br />

vapor up the fractionating column at the same time. Hot vapor will make the<br />

condensed vapor boils again. It will contain more and more ethanol as the vapor<br />

rises up to the fractionating column.<br />

Fig.(8): Fractional distillation<br />

29

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