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Fundamental Organic Chemistry

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NO 2<br />

+ H 2<br />

O<br />

HNO 3<br />

Conc.<br />

H 2<br />

SO 4<br />

Conc.<br />

Nitrobenzene<br />

…(8)<br />

CH 3<br />

2-Toluene<br />

Toluene is a color less liquid , the boiling point is 110°C immiscible in water but<br />

miscible in organic solvent behave like benzene on burning .<br />

Test Observation Result<br />

1-Nitration Test :<br />

In a test tube put 1ml of<br />

conc.HNO 3 acid + 1ml of conc.<br />

H 2 SO 4 acid + 0.5ml of Toluene<br />

then pour into beaker contains<br />

cold water .<br />

Yellow oily layer will<br />

be separated<br />

The yellow oily layer is<br />

o-Nitrotoluene<br />

& p-Nitrotoluene (9).<br />

CH 3<br />

HNO 3<br />

Conc.<br />

H 2<br />

SO 4<br />

Conc.<br />

CH 3<br />

CH 3<br />

NO 2<br />

NO 2<br />

+<br />

….(9)<br />

o-Nitrotoluene<br />

p-Nitrotoluene<br />

39

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