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Fundamental Organic Chemistry

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OH<br />

2-Resorcinol<br />

OH<br />

Resorcinol is solid ,dissolve in water and alcohol but in soluble in benzene.<br />

Test Observation Result<br />

1-Ferric chloride test:<br />

Diluted solution of resorcinol in alcohol then<br />

add 2 drop of FeCl 3 .<br />

Deep violet color<br />

appear<br />

The compound<br />

from phenols<br />

2-Azo dye formation test:<br />

Take 3 test tube<br />

Tube (1): 1ml of aniline + 3.5ml of conc. HCl<br />

Tube (2): 1ml of sodium nitrite NaNO 2<br />

Tube (3): resorcinol dissolved in excess NaOH.<br />

Red dye The dye is<br />

Benzene azo<br />

resorcinol<br />

Keep the 3 test tube in ice bath & Put tube<br />

(2) (1) slowly, then add mixture to tube (3).<br />

3-Chloroform test :<br />

1ml of resorcinol dissolved in excess 20% NaOH<br />

+1ml of chloroform CHCl 3 then heat in water bath<br />

Red fluorescent Compound is<br />

resorcinol<br />

4-Phethalen test:<br />

In dry test tube add 0.5gm of resorcinol<br />

+ 0.5 gm of phthalic anhydride +2drop of<br />

conc.H 2 SO 4 , and gently fuse together allow to<br />

cool , and then add 30% NaOH solution in excess<br />

Red fluorescent<br />

in the inner &<br />

Green fluorescent<br />

in the wall.<br />

Compound is<br />

resorcinol<br />

72

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