18.03.2014 Views

Fundamental Organic Chemistry

Fundamental Organic Chemistry

Fundamental Organic Chemistry

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

To Make Neutral Solution N.S.:<br />

Add to the acid aqueous NH 3 (NH 4 OH) till the solution is just alkaline to litmus.<br />

Boil the solution until the evolution of NH 3 gas ceases ( this can be ensured by<br />

exposing a red litmus paper to vapor ) .<br />

General properties for acids :<br />

1. Soluble in sodium hydroxide.<br />

2. Soluble in sodium carbonate or sodium bicarbonate with eff. of CO 2 gas.<br />

3. When heated the acids with sodalime CO 2 evolved.<br />

COOH<br />

CaO/NaOH<br />

heat + CO 2<br />

COOH<br />

OH<br />

CaO/NaOH<br />

heat<br />

OH<br />

+ CO 2<br />

1. Acids react with alcohol in present of conc. H 2 SO 4 produce ester with specific<br />

odor .<br />

'<br />

RCOOH + ROH<br />

'<br />

H 2 SO 4 '<br />

RCOOR H 2 O<br />

+<br />

2. N.S of acid with ferric chloride solution. Gives specific color for each acid.<br />

3. Acids Solution turns litmus paper to red.<br />

54

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!