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guide to thin section microscopy - Mineralogical Society of America

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Guide <strong>to</strong> Thin Section Microscopy<br />

Optical properties: basic principles<br />

Crystals <strong>of</strong> orthorhombic, monoclinic and triclinic symmetry<br />

The propagation <strong>of</strong> both waves in crystals <strong>of</strong> such symmetry is direction-dependent. The<br />

resulting 3D two-surface models <strong>of</strong> ray velocities are complicated and have not had any<br />

impact on practical work. Microscopists prefer the single-surface indicatrix model for the<br />

explanation <strong>of</strong> optical phenomena (Fig. 4-7).<br />

Figure 4-7. Optically biaxial crystals, crystal symmetry and indicatrix<br />

The indicatrix <strong>of</strong> crystals with orthorhombic, monoclinic and triclinic symmetry is respresented<br />

in a coordinate system with axes X, Y, Z that are orthogonal <strong>to</strong> each other. The geometry<br />

<strong>of</strong> the triaxial ellipsoid is defined by the proportional lengths <strong>of</strong> the refractive indices n x , n y ,<br />

n z on X, Y and Z. Thus, the symmetry <strong>of</strong> the ellipsoid is generally orthorhombic. The<br />

refractive indices are defined as n z > n y > n x (or n γ > n β > n α ).<br />

There are two circular <strong>section</strong>s with the radius n y . Orthogonal <strong>to</strong> these circular <strong>section</strong>s, light<br />

propagates with the same velocity as in an isotropic substance. These two directions correspond<br />

<strong>to</strong> the two optic axes A. The low-symmetry crystals are therefore optically anisotropicbiaxial.<br />

Raith, Raase & Reinhardt – February 2012<br />

The optic axes lie in the ZX plane (= optic axial plane OAP). Y is orthogonal <strong>to</strong> the OAP. The<br />

angle between the optic axes (2V) is mineral-specific and can attain values between 0˚ and<br />

90˚. If Z dissects the acute angle (2V z < 90˚), the crystal is biaxial-positive; if X dissects the<br />

acute angle (2V x < 90˚), the crystal is biaxial-negative. If the axial angle is 90˚, the crystal is<br />

optically neutral.<br />

The spatial orientation <strong>of</strong> the indicatrix in a crystal is defined by the crystal's symmetry:<br />

• In crystals <strong>of</strong> orthorhombic symmetry, the ellipsoid axes (X, Y, Z) correspond <strong>to</strong> the<br />

crystallographic axes (a,b,c). Which indicatrix axis is parallel <strong>to</strong> which crystallographic<br />

axis depends on the specific mineral.<br />

• In crystals <strong>of</strong> monoclinic symmetry, it is only the crystallographic b axis and one <strong>of</strong> the<br />

indicatrix axes that are parallel (commonly Y). The other two axes lie in the symmetry<br />

plane (010) and form angles with the crystallographic axes a and c.<br />

• In triclinic crystals, none <strong>of</strong> the axes <strong>of</strong> the orthorhombic indicatrix is parallel <strong>to</strong> any <strong>of</strong> the<br />

crystallographic axes. The indicatrix axes form mineral-specific angles with the crystallographic<br />

axes.<br />

67

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