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guide to thin section microscopy - Mineralogical Society of America

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Guide <strong>to</strong> Thin Section Microscopy<br />

Double refraction<br />

Interference colours:<br />

In contrast <strong>to</strong> monochromatic light, the use <strong>of</strong> white light provides a full spectrum <strong>of</strong> wavelengths<br />

(spectral colours) which, for a given retardation, is modified in the analyzer through<br />

interference such that certain wavelengths are transmitted at full intensity; others are reduced<br />

<strong>to</strong> a variable degree or are obliterated entirely. White light exiting a colourless anisotropic<br />

crystal comprises an infinite number <strong>of</strong> wave couples corresponding <strong>to</strong> all spectral colours,<br />

each wavelength represented by a wave couple with mutually orthogonal vibration directions<br />

that are fixed by the crystal's orientation (cf. Figs. 4-25A and B which show such single wave<br />

couples). Interference in the analyzer between the two waves <strong>of</strong> each couple across the light<br />

spectrum is a way <strong>of</strong> making retardation visible and also quantifiable. Any specific<br />

retardation modifies the full white-light spectrum, generating a characteristic wavelength<br />

spectrum and wave amplitude pattern, which in combination produce a unique interference<br />

colour. Evidently, interference colours can only be generated from polychromatic light. They<br />

correlate directly with retardation. The sequence <strong>of</strong> interference colours in relation <strong>to</strong><br />

increasing retardation is explained graphically in Figs. 4-27 and 4-28.<br />

Raith, Raase & Reinhardt – February 2012<br />

Figure 4-27. Constructive and destructive interference as a function <strong>of</strong> wavelength λ and<br />

retardation Γ in the spectral range <strong>of</strong> visible light (see also Fig. 4-28). The variation <strong>of</strong> the<br />

intensity <strong>of</strong> the light being transmitted by the analyzer is described by the equation I =<br />

100[sin 2 (Γ/λ)180°].<br />

To give a few examples: In the lower range <strong>of</strong> retardation (Γ = 0 ↔ 200 nm) black and grey<br />

colour <strong>to</strong>nes dominate as the complete colour spectrum <strong>of</strong> white light is affected by a<br />

reduction <strong>of</strong> intensities. At around Γ = 250 nm only wavelengths from both ends <strong>of</strong> the<br />

spectrum are slightly diminished which is perceived as close <strong>to</strong> white ("first-order white").<br />

The range Γ = 400 ↔ 500 nm shows characteristic orange <strong>to</strong> light red interference colours, as<br />

blue and green wavelengths are suppressed, while longer wavelengths dominate the spectrum.<br />

This situation is reverse in the range Γ = 600 ↔ 650 nm. Here, the shorter wavelengths<br />

dominate, which results in a blue interference colour. The distinctive purple colour at Γ = 551<br />

nm ("first-order red") lies in a position where the intermediate wavelengths (green <strong>to</strong> orange)<br />

89

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