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guide to thin section microscopy - Mineralogical Society of America

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Guide <strong>to</strong> Thin Section Microscopy<br />

Colour and pleochroism<br />

Pleochroic minerals <strong>of</strong> tetragonal, hexagonal and trigonal symmetry show two specific<br />

absorption colours (dichroism), parallel <strong>to</strong> the vibration directions <strong>of</strong> the E- and O-waves.<br />

Sections orthogonal <strong>to</strong> the crystallographic c-axis (= optic axis) generally show the absorption<br />

colour <strong>of</strong> the O-wave as the microscope stage is rotated. Sections parallel <strong>to</strong> the c-axis show<br />

an alternation between the absorption colour <strong>of</strong> the E-wave (E-W orientation <strong>of</strong> the c-axis)<br />

and the O-wave (N-S orientation <strong>of</strong> the c-axis) for every 90° rotation <strong>of</strong> the stage (Fig. 4-11<br />

and Fig. 4-12: example <strong>to</strong>urmaline).<br />

Figure 4-11. Change <strong>of</strong> absorption colour <strong>of</strong> <strong>to</strong>urmaline during a 360° rotation <strong>of</strong> the<br />

microscope stage. Shown are the four positions <strong>of</strong> a crystal <strong>section</strong> in which the vibration<br />

directions <strong>of</strong> the two waves coincide exactly with the directions <strong>of</strong> the polarizers. In these<br />

orientations, only the E-W vibrating wave passes the crystal; the N-S wave is not activated.<br />

Pleochroic minerals <strong>of</strong> orthorhombic, monoclinic and triclinic symmetry possess three<br />

characteristic absorption colours (trichroism) related <strong>to</strong> vibration directions parallel <strong>to</strong> the<br />

principal indicatrix axes X, Y and Z. The determination <strong>of</strong> these colours must be performed<br />

on selected crystal <strong>section</strong>s that are parallel <strong>to</strong> two <strong>of</strong> these axes (Fig. 4-14 A-C). The relation<br />

between crystal orientation, vibration direction and absorption (pleochroism) for members <strong>of</strong><br />

the amphibole group is explained in Figs. 4-15,16,17. As the example <strong>of</strong> the amphiboles<br />

demonstrates beautifully, there is a correlation between absorption colour and chemical<br />

composition (Fig. 4-13).<br />

Raith, Raase & Reinhardt – February 2012<br />

Figure 4-13. Colours <strong>of</strong> amphiboles <strong>of</strong> different composition, in relation <strong>to</strong> the principal<br />

vibration direction parallel b. The amphibole grains are oriented such that the b-axis is in<br />

alignment with the lower polarizer. In these minerals, b is parallel <strong>to</strong> the indicatrix axis Y.<br />

Hence, the colours displayed correlate with Y (cf. Fig. 4-15).<br />

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