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Annual Report 2006 - Plataforma Solar de Almería

Annual Report 2006 - Plataforma Solar de Almería

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ENVIRONMENTAL APPLICATIONS OF SOLAR ENERGY<br />

4.2.1 FOTODETOX<br />

Elimination of persistent pollutants by advanced oxidation.<br />

http://www.psa.es/webesp/projects/foto<strong>de</strong>tox/in<strong>de</strong>x.html<br />

Participants: Univ. of Almería Dept. of Chemical Engineering; Polytechnic<br />

Univ. of Valencia Dept. of. Textile Engineering; CIEMAT-PSA (coordinator).<br />

Contact:<br />

Funding:<br />

Dr. S. Malato, sixto.malato@psa.es<br />

National RD&I Plan, MEC. CIEMAT budget: 80 K€ + 1 FPI Ph.D.<br />

Fellowship.<br />

Duration: December 2003 – December <strong>2006</strong><br />

Motivation:<br />

Treatment of water containing pestici<strong>de</strong>s by combined biological<br />

and photocatalytic treatment.<br />

Purposes:<br />

1) Pilot-plant solar photocatalytic (photo-Fenton and TiO2) treatment of<br />

water containing pestici<strong>de</strong>s. Find optimum operating parameters.<br />

2) Study of bio<strong>de</strong>gradability using monospecific bacteria cultures (selected<br />

from among those commonly used in WTPs) in pestici<strong>de</strong>polluted<br />

water partly treated by photocatalysis. Evaluation of the bacteria<br />

strains that are the most active in bio<strong>de</strong>grading pollutants.<br />

3) Development of predictive mo<strong>de</strong>ls for bio<strong>de</strong>gradability of water partly<br />

treated by photocatalysis.<br />

4) Study of the bio<strong>de</strong>gradability (using real activated sludge from WTPs)<br />

of pestici<strong>de</strong>-polluted water partly treated by photocatalysis.<br />

5) Development of a bioreactor specially adapted to this kind of water<br />

partly treated by photocatalysis.<br />

6) Pre<strong>de</strong>sign of a solar photocatalytic water treatment plant for pretreating<br />

water containing persistent pollutants and make them compatible<br />

with municipal WTP input requirements.<br />

Objectives achieved in <strong>2006</strong>:<br />

The objectives set for 2004 and 2005 were met (see PSA <strong>Annual</strong> <strong>Report</strong>s<br />

2004 and 2005), and during <strong>2006</strong>, work was mainly related to Objectives 4, 5<br />

and 6.<br />

Biological processes are among the simplest and economical treatment<br />

techniques available, and it therefore makes good sense to combine them<br />

with photo-Fenton, since the <strong>de</strong>gradation of non-bio<strong>de</strong>gradable pollutants is<br />

normally coupled with both reduced toxicity and increased bio<strong>de</strong>gradability.<br />

Our proposal is a combination of quick analysis techniques (COD, TOC, toxicity)<br />

that would assist in making a <strong>de</strong>cision as to which parameters to use for<br />

estimating or measuring the bio<strong>de</strong>gradability of water. Once the plant is in<br />

continuous operation, just one of the above parameters might even be<br />

enough for an experienced operator to make this <strong>de</strong>cision.<br />

Below we propose a working methodology for fast techniques to predict<br />

when water is bio<strong>de</strong>gradable. One of these parameters is called “Average Oxidation<br />

State” (AOS), which can be calculated by the following equation, where<br />

TOC (Total Organic Carbon and COD (Chemical Oxygen Demand) are expressed<br />

in moles of C L -1 and O 2 L -1 , respectively.<br />

73

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