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tivity on the carmel faul

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terrain (see ch. 1.4- Geological setting of Carmel regi<strong>on</strong>), yet no direct evidence of<br />

slope movement in <strong>the</strong> area of Denya Cave was found to date. Landslides were<br />

documented mostly <strong>on</strong> <strong>the</strong> nor<strong>the</strong>astern slopes of <strong>the</strong> Carmel.<br />

The eliminati<strong>on</strong> of <strong>the</strong>se points allows for <strong>the</strong> working hypo<strong>the</strong>sis that earthquakes<br />

caused <strong>the</strong> observed damage to speleo<strong>the</strong>ms in Denya Cave.<br />

1.3 Dating of Speleo<strong>the</strong>ms<br />

In <strong>the</strong> 238 U radioactive decay-series a state of secular equilibrium between parent and<br />

daughter nuclides is established in any naturally occurring material that has remained<br />

undisturbed for several milli<strong>on</strong> years because <strong>the</strong> half-life of <strong>the</strong> parent isotope is much greater<br />

than that of <strong>the</strong> intermediate daughters in <strong>the</strong> decay chain. The decay-series in sec<strong>on</strong>dary<br />

deposits formed from <strong>the</strong> dissoluti<strong>on</strong> and subsequent precipitati<strong>on</strong> of such material, however,<br />

will be in a state of disequilibrium at time of formati<strong>on</strong>, with ei<strong>the</strong>r an excess or deficiency of<br />

intermediate nuclides because of fracti<strong>on</strong>ati<strong>on</strong> processes. The extent to which it has returned to<br />

secular equilibrium in a closed system from an initial state of disequilibrium can be expressed<br />

by a straightforward functi<strong>on</strong> of time using <strong>the</strong> decay c<strong>on</strong>stants if <strong>the</strong> following criteria are<br />

satisfied: (1) intermediate and daughter decay products at time of formati<strong>on</strong> were absent, or if<br />

present, can be corrected for; (2) no gain or loss of <strong>the</strong> parent nuclide or daughter products<br />

occurred since <strong>the</strong> time of formati<strong>on</strong> (Richards and Dorale, 2003).<br />

U-series dating of speleo<strong>the</strong>ms is based <strong>on</strong> <strong>the</strong> extreme fracti<strong>on</strong>ati<strong>on</strong> of <strong>the</strong> parent 238 U<br />

isotope from its l<strong>on</strong>g-lived daughter 230 Th in <strong>the</strong> hydrosphere. The average abundances of U<br />

and Th in <strong>the</strong> earth’s c<strong>on</strong>tinental crust are 1.7 and 8.5 µg/g respectively (Wedepohl, 1995).<br />

Their relative abundances in <strong>the</strong> hydrosphere are different principally because of <strong>the</strong>ir differing<br />

solubility in surface and near surface envir<strong>on</strong>ments (Richards and Dorale, 2003).<br />

U is readily mobilized in <strong>the</strong> meteoric envir<strong>on</strong>ment, principally as <strong>the</strong> highly soluble<br />

Uranyl i<strong>on</strong> (UO 2+ 2 ). The l<strong>on</strong>g-lived daughter product Th exists in a +4 oxidati<strong>on</strong> state and is<br />

readily hydrolyzed and ei<strong>the</strong>r precipitated or absorbed <strong>on</strong> detrital particulates. It can <strong>the</strong>refore<br />

be readily transported with <strong>the</strong> result that waters feeding sec<strong>on</strong>dary calcite deposits will<br />

generally have negligible Th c<strong>on</strong>centrati<strong>on</strong>s. In a closed system, <strong>the</strong> extent to which 230 Th/ 238 U<br />

ac<str<strong>on</strong>g>tivity</str<strong>on</strong>g> (a) ratios have returned to unity is a functi<strong>on</strong> of time (t).<br />

Calcite speleo<strong>the</strong>ms can be dated accurately by U-series disequilibrium techniques under<br />

specific c<strong>on</strong>diti<strong>on</strong>s: (1) when <strong>the</strong> system remained closed to <strong>the</strong> additi<strong>on</strong> or removal of U or Th<br />

nuclides to <strong>the</strong> lattice; (2) when <strong>the</strong> deposit is younger than ~500,000y; (3) when <strong>the</strong>re is a<br />

sequential stratigraphic layering al<strong>on</strong>g <strong>the</strong> growth axis; (4) when <strong>the</strong>re is no initial Th in <strong>the</strong><br />

14

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