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tivity on the carmel faul

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Table 3: Isochr<strong>on</strong> sample's results of low detrital c<strong>on</strong>tent samples: a. Calculated isotopic ratios<br />

and ages. b. Calculated slopes and y-axis intercepts for correcti<strong>on</strong> factor calculati<strong>on</strong>s. Isochr<strong>on</strong><br />

plot: yellow-DN-4 pre, red-DN-6c pre, green-DN-7 pre, blue-DN-7 post. Unreliable results are<br />

marked in orange.<br />

a<br />

Sample name 230/234 err 234/230 err 232/234 err 230/232 err Age(y) + -<br />

DN-4 pre (top) 0.14265 0.00169 7.01033 0.08305 0.013535 0.000016 10.54 0.13 16717 214 214<br />

DN-4 pre II (post) 0.16915 0.00276 5.91195 0.09649 0.025442 0.000032 6.65 0.11 20132 362 361<br />

DN 4 pre 0.16814 0.00134 5.94752 0.04748 0.001572 0.000002 106.97 0.87 19981 175 175<br />

DN3y(dn4-pre) 0.20100 0.00267 4.97501 0.06616 0.006784 0.000008 29.63 0.41 24343 364 362<br />

Sample name 230/234 err 234/230 err 232/234 err 230/232 err Age(y) + -<br />

DN8y(dn6C pre) 0.14291 0.00280 6.99729 0.13702 0.023083 0.000026 6.19 0.12 16749 355 354<br />

DN7y(dn6C pre) 0.28225 0.00319 3.54296 0.04006 0.001928 0.000003 146.36 1.67 35921 483 481<br />

DN 6C pre 0.27134 0.00237 3.68536 0.03222 0.001525 0.000001 177.99 1.57 34300 352 352<br />

DN-6c pre I 0.18607 0.00207 5.37436 0.05989 0.019748 0.000027 9.42 0.11 22317 276 276<br />

DN-6c pre II 0.27851 0.00236 3.59048 0.03039 0.003278 0.000005 84.97 0.78 35363 354 354<br />

Sample name 230/234 err 234/230 err 232/234 err 230/232 err Age(y) + -<br />

DN 7 pre 0.20218 0.00145 4.94600 0.03553 0.010228 0.000011 19.77 0.15 24511 198 198<br />

DN-7-45 0.26418 0.00166 3.78527 0.02379 0.010182 0.000014 25.95 0.17 33202 245 245<br />

DN-7-43 0.29038 0.00254 3.44376 0.03012 0.001742 0.000002 166.70 1.50 37142 389 388<br />

DN-7-44 0.28619 0.00171 3.49419 0.02083 0.001982 0.000004 144.37 0.86 36515 262 262<br />

Sample name 230/234 err 234/230 err 232/234 err 230/232 err Age(y) + -<br />

DN 7 post 0.10624 0.00123 9.41238 0.10919 0.007832 0.000008 13.56 0.16 12206 150 150<br />

DN 7postB 0.09668 0.00067 10.34369 0.07126 0.007685 0.000008 12.58 0.09 11050 80 80<br />

DN-7-46 0.10627 0.00134 9.40958 0.11876 0.004735 0.000007 22.44 0.29 12208 163 163<br />

DN-7-46b-post 0.08100 0.00166 12.34566 0.25263 0.002975 0.000006 27.23 0.56 9181 196 196<br />

DN-7-47 0.09181 0.00134 10.89230 0.15885 0.002397 0.000002 38.30 0.56 10464 160 160<br />

b<br />

DN-4 pre Slope ± Intersect ± 230/232d 232/238d Av. 232/238d<br />

all -8 82 0.27 0.99 -10.9589 -0.278221 0.076689247<br />

No DN3y 31 9700 0 130 31 0.098355<br />

DN-6c Slope ± Intersect ± 230/232d 232/238d<br />

all -6 1.8 0.292 0.025 -8.474576 -0.359782<br />

partI -5.2 2.4 0.289 0.025 -7.313643 -0.416892<br />

partII 12 310 0.25 0.69 16 0.190563<br />

DN-7 pre Slope ± Intersect ± 230/232d 232/238d<br />

all 174 430 2.9 3 -91.57895 -0.033294<br />

DN-7 post Slope ± Intersect ± 230/232d 232/238d<br />

all 6 12 0.066 0.067 6.423983 0.009531<br />

230 Th/<br />

234 U<br />

0.30<br />

0.26<br />

0.22<br />

0.18<br />

0.14<br />

0.10<br />

data-point error crosses are 2σ<br />

No-47 7 26 0.05 0.16 7.368421 0.008309 0.06<br />

0.00 0.04<br />

232 Th/ 234 U<br />

In order to determine <strong>the</strong> nature of <strong>the</strong> detrital comp<strong>on</strong>ent found in samples from<br />

Denya Cave and to establish its origin, four different speleo<strong>the</strong>m samples were dissolved<br />

with two different methods. Part of <strong>the</strong> sample was dissolved with weak acetic acid,<br />

which <strong>on</strong>ly dissolves <strong>the</strong> carb<strong>on</strong>ate comp<strong>on</strong>ent and does not affect <strong>the</strong> clays, and <strong>the</strong> o<strong>the</strong>r<br />

underwent total dissoluti<strong>on</strong> with HNO 3 and HF (see Appendix II-I,II). The samples that<br />

were treated with acetic acid were <strong>the</strong>n placed in a centrifuge, which enabled <strong>the</strong><br />

separati<strong>on</strong> of all insoluble matter (Appendix II-I,II). A comparis<strong>on</strong> of 230 Th/ 232 Th ratios<br />

between <strong>the</strong> two methods can be seen in Table 4. Three observati<strong>on</strong>s can be discerned<br />

from <strong>the</strong> results of this experiment; (1) 230 Th/ 232 Th is quite low (

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