CH-TRAMPAC - Waste Isolation Pilot Plant - U.S. Department of ...

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CH-TRAMPAC Document Rev. 2, May 2005Table 4.3-8 – Allowable Materials for Waste Material Type IV.1 Solidified OrganicsAny material in Waste Types I, II, or III (Table 4.3-1 through Table 4.3-7)Acids, organicAlcohols (e.g., butanol, ethanol, isopropanol, methanol)Esters (e.g., ethyl acetate, polyethylene glycol ester)Ethers (e.g., ethyl ether)Halogenated organics (e.g., bromoform; carbon tetrachloride; chlorobenzene; chloroform; 1,1-dichloroethane;1,2-dichloroethane; 1,1-dichloroethylene; cis-1,2-dichloroethylene; methylene chloride;1,1,2,2-tetrachloroethane; tetrachloroethylene; 1,1,1- trichloroethane; 1,1,2-trichloroethane;trichloroethylene; 1,1,2-trichloro-1,2,2-trifluoroethane)Hydrocarbons, aliphatic (e.g., cyclohexane, n-paraffin hydrocarbons)Hydrocarbons, aromatic (e.g., benzene; ethyl benzene; toluene; 1,2,4-trimethylbenzene; 1,3,5-trimethylbenzene;xylene)Ketones (e.g., acetone, methyl ethyl ketone, methyl isobutyl ketone)Trioctyl phosphine oxideNote: Other chemicals or materials not identified in this table are allowed provided that they meet the requirements ofSection 4.3.1. All materials in the final waste form must be inert (nonreactive), be in a nonreactive form, orhave been rendered nonreactive.4.3-10
CH-TRAMPAC Document Rev. 2, May 20054.4 Chemical CompatibilityThe lists of allowable materials in Table 4.3-1 through Table 4.3-8 restrict the chemicalcomposition of the payload. The basis for evaluating chemical compatibility is theU.S. Environmental Protection Agency (EPA) document “A Method for Determining theCompatibility of Hazardous Wastes” (EPA-600/2-80-076). 1 This method provides a systematicmeans of analyzing the chemical compatibility for specific combinations of chemical compoundsand materials. Any incompatibilities between the payload and the packaging shall be evaluatedseparately if not covered by the EPA method. 1 As described in Appendix 6.1 of the CH-TRUPayload Appendices 2 , the EPA method classifies individual chemical compounds into chemicalgroups and identifies the potential adverse reactions resulting from incompatible combinations ofthe groups.4.4.1 RequirementsChemical compatibility shall be ensured for the following four conditions:• Chemical compatibility of the waste form within each individual payload container• Chemical compatibility between contents of payload containers during hypotheticalaccident conditions• Chemical compatibility of the waste forms with the TRUPACT-II and HalfPACT ICV• Chemical compatibility of the waste forms with the TRUPACT-II and HalfPACT O-ringseals.4.4.2 Methods of Compliance and VerificationCompatibility of all waste material types has been demonstrated for transport in theTRUPACT-II and HalfPACT using the chemicals listed in Table 4.3-1 through Table 4.3-8. Therestrictions imposed on the chemical constituents of the content codes approved by the WIPPCH-TRU Payload Engineer ensure compliance with the compatibility requirements (see alsoAppendices 6.1, 6.2, 6.3, and 6.4 of the CH-TRU Payload Appendices 2 ). The chemical list foreach content code is formally documented by the site.1 Hatayama, H.K., Chen, J.J., de Vera, E.R., Stephens, R.D., and Storm, D.L., 1980, A Method for Determining theCompatibility of Hazardous Wastes, EPA-600/2-80-076, U.S. Environmental Protection Agency, Cincinnati, Ohio.2 U.S. Department of Energy (DOE), CH-TRU Payload Appendices, U.S. Department of Energy, Carlsbad FieldOffice, Carlsbad, New Mexico.4.4-1
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