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PHYSICS

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••,,<br />

""<br />

. .<br />

~: . , .. - .<br />

......,<br />

40<br />

}!<br />

'"......•;<br />

,<br />

- .-­<br />

..-';": .<br />

',~<br />

t 'j ::<br />

;:. - . <<br />

HII<br />

a<br />

Fig. 21.14. Diffraction pattern<br />

obtained from a helical structure<br />

of DNA<br />

cross-wise pattern of the DNA X-ray<br />

diffraction picture (fig. 21.14) was<br />

due to a repeating helical structure.<br />

21.3.9. Polarization<br />

JIll<br />

b<br />

~, ",<br />

'.~<br />

Ull<br />

--­ ",<br />

'~<br />

Ell<br />

,......,<br />

..<br />

, ..<br />

Fig. 21.15. Representation of the vector jj; of: a ­ unpolarized light;<br />

b ­ linearly polarized light; c ­ circularly polarized light;<br />

d ­ elliptically polarized light. The light ray is travelling at right<br />

angles to the plane of the paper<br />

152<br />

Light is electromagnetic radiation consisting of electric (jj;)<br />

and magnetic (H) vectors vibrating at right angles to each other<br />

and to the direction of propagation..Conventional polarization is<br />

associated with the electric vector. An ordinary beam of light is<br />

produced by a large number of waves emitted by the atoms or<br />

molecules of the light source; the direction of vibration of the jj;<br />

c<br />

\<br />

"',<br />

d<br />

, , ....<br />

,<br />

\, , ,<br />

I I<br />

I,<br />

vector changes about every 10- 8 seconds. A wave of unpolarized<br />

light traveling at right angles to a plane perpendicular to the<br />

direction of propagation is depicted in fig. 21.15, a.<br />

A wave is said to be linearly polarized if jj; vibrates in the same<br />

direction at all times at a particular point (fig. 21.15, b).<br />

If the tip of the vector jj; rotates in a circle with time, the<br />

wave is said to be circularly polarized (fig. 21.15, c).<br />

If the ti p of the vector jj; moves in an elli pse, the wave is<br />

said to be elliptically polarized (fig. 21.15, d).<br />

There are some special dichroic crystals (e.g., tourmaline)<br />

and Polaroid films (polyvinyl alcohol) that will pass light vibrating<br />

in only one direction. Such a crystal is called the polarizer.<br />

If the light is plane polarized after passing through the crystal, it<br />

will be stopped by an analyzer placed at right angles to the polarizer.<br />

Optical activity is the ability of certain materials to rotate the<br />

plane of polarization of transmitted light. The angle (cp) through<br />

which the light is rotated by the material depends on the length<br />

(l) of the sample and on the concentration (C) if the substance<br />

is in solution:<br />

Source<br />

of light<br />

II<br />

Polarizer<br />

21.3.10. Optical Activity<br />

qJ = aCI<br />

where a is the specific optical activity of the substance.<br />

a<br />

lj I<br />

- ­ -1 1/7<br />

Optical cell<br />

Fig. 21.16. Polarymeter<br />

Analyizer<br />

(21.13)<br />

----+1 Registered<br />

system<br />

153

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