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Distribution of Chlorinated Hydrocarbon Pesticides and PCBs in the ...

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silicate <strong>and</strong> orthophosphate were approximately 6, 15 <strong>and</strong> 1.4<br />

pM respectively on both occasions. Phosphate concentrations<br />

<strong>in</strong> <strong>the</strong> upper 50 m decreased to 1 pm <strong>in</strong> August. A11 nutrient<br />

concentrations were dramatically lower dur<strong>in</strong>g August <strong>in</strong> <strong>the</strong><br />

upper 5 m. The very low phosphate (0.3 pm) , silicate (6 pm)<br />

<strong>and</strong> nitrate (1 pm) concentrations observed <strong>in</strong> this water is<br />

likely a result <strong>of</strong> ice melt <strong>and</strong> run-<strong>of</strong>f from <strong>the</strong> isl<strong>and</strong>.<br />

Increased concentrations <strong>of</strong> suspended particulate organic<br />

carbon <strong>in</strong> August (Table 4.4) <strong>and</strong> reduced nutrient<br />

concentrations <strong>in</strong> <strong>the</strong> upper well m-ixed layer reflect <strong>the</strong> net<br />

<strong>in</strong>crease <strong>in</strong> suspended particulate matter due to primary<br />

production by phytoplankton <strong>and</strong> ice algae. With<strong>in</strong> <strong>the</strong> upper<br />

part <strong>of</strong> <strong>the</strong> halocl<strong>in</strong>e, a dist<strong>in</strong>ct nutrient maximum was<br />

observed on all three sampl<strong>in</strong>g trips at a depth <strong>of</strong> between<br />

100 - 120 m <strong>and</strong> a sal<strong>in</strong>ity <strong>of</strong> 33.1 ppt. Concentrations <strong>of</strong><br />

dissolved silicate, nitrate <strong>and</strong> orthophosphate reached levels<br />

<strong>of</strong> 38, 17 <strong>and</strong> 2.2 pM respectively <strong>in</strong> June. Maximum phosphate<br />

was lower <strong>in</strong> August (1.8 pM) <strong>and</strong> nitrate lower <strong>in</strong> May (15<br />

pM). This maximum is a dist<strong>in</strong>ctive feature <strong>of</strong> <strong>the</strong> Central<br />

Arctic Ocean which has been postulated <strong>in</strong> recent publications<br />

to have its orig<strong>in</strong>s with<strong>in</strong> <strong>the</strong> Arctic Bas<strong>in</strong> ra<strong>the</strong>r than with<br />

<strong>in</strong>trud<strong>in</strong>g Ber<strong>in</strong>g Sea water. The mechanism suggested is br<strong>in</strong>e<br />

formation <strong>and</strong> dra<strong>in</strong>age from <strong>the</strong> large cont<strong>in</strong>ental shelves<br />

(Jones <strong>and</strong> Anderson, 1987; Mell<strong>in</strong>g <strong>and</strong> Lewis, 1982; Aagaard<br />

- et &., 1981, 1985). Nutrient depth pr<strong>of</strong>iles for all three<br />

trips are shown <strong>in</strong> Figures 4.3 - 4.5.<br />

4.4.2 Particulate Orsanic Carbon <strong>and</strong> Nitrsqen<br />

The suspended matter, particulate organic carbon (POC)<br />

<strong>and</strong> particulate organic nitrogen (PON) concentrations for a%P<br />

three trips are summarized <strong>in</strong> Table 4.4. Values at all<br />

depths (except 125 m) were generally lower than<br />

concentrations measured by Gordon <strong>and</strong> Cranford (1985) at a<br />

deep water sampl<strong>in</strong>g site (85'~, 2000 m) <strong>in</strong> <strong>the</strong> Canada Bas<strong>in</strong><br />

where concentrations <strong>of</strong> suspended particles might be

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