NATIONAL INSTITUTE OF TECHNOLOGY KARNATAKA, SURATHAKAL ------------------------------------------------------------------------------------------------------------------ CY400 BIO-INORGANIC CHEMISTRY (3–0–0) 3 Introduction. Transport and storage <strong>of</strong> metal ions. Elements <strong>of</strong> Biology and Medicine. Energy <strong>of</strong> biological systems. Hydrogen Biochemistry. The functional value <strong>of</strong> the chemical elements in Biological systems. Sodium, Potassium, Chlorine, Magnesium, Cadmium, Zinc, Iron, Manganese, Copper, Cobalt, Molybdenum, Vanadium, Tungsten, Phosphorus, Sulphur, Sele-nium, Halogen. Metal based dr<strong>ug</strong>s. Environmental application and toxic effects <strong>of</strong> metal ions. M. Satake & Y. Mido, Bioinorganic Chemistry, Discovery Publ House, New Delhi, 2001. H. Siegel & T. G. Spiro, Metalions <strong>of</strong> Biological Systems, Mercel-Dekker,1980 to present. CY401 CHEMISTRY OF DYES AND PIGMENTS (3–0–0) 3 Dyes � Color and constitution, chromophores and auxochromes, insulating groups, Classification based on chemical constitution and applications. Preparation, properties and uses <strong>of</strong> dye intermediates and dyes. Photochemistry �Principles, photo induced reactions, oxidation, reduction, isomerization, addition reactions. Woodward H<strong>of</strong>fmann�s rule. Inks � composition, pigments, vehicles, ink additives, Ink manufacture, printing methods and screen printing. Inorganic pigments. The chemistry <strong>of</strong> synthetic dyes and pigments, American Chemical Society Monograph Series, Hagger Pub. Co., 1970. K. Venkataraman, The chemistry <strong>of</strong> synthetic dyes, Academic Press Inc. 1980. D. E. Bissett, Printing Ink <strong>Technology</strong>, Northwood, 1978. CY402 SURFACE MODIFICATIONS (3–0–0) 3 Introduction. Plating and Coating Processes: Basic principles and methods. Hardfacing. Anodising. PVD. CVD. Thermal spraying. Electrodeposition. Electroless deposition. Hot dipping. Composite coating. Surface alloying. Alloy plating. Thermal processes: Laser -hardening, glazing, surface alloying, cladding. Electron beam hardening. Implantation and special processes: Ion implantation. CMM coating. Applications and recent developments. T. S. Sudarshan (Ed), Surface Modification Technologies, Marcel Dekker, 1989. V. Vasantasree and P. S. Sidky, Metallic and Ceramic Coatings, Longman Scientific and Technical, UK, 1989. CY403 WATER AND SOIL CHEMISTRY (3–0–0) 3 Water resources. Physical chemistry <strong>of</strong> sea water. Complexation in natural water and waste water. Microbialy mediated redox reactions. Ion-water interactions. Water Pollution: Water pollutants, waste water treatment, trace elements in water, water quality parameters and standards, sampling, preservation and monitoring techniques. Soil-ion interactions and chemical cycles. Solute-solute interactions. Weathering and soil development processes. Soil organic matter. Soil and microorganism. Cation, anion and molecular interactions in soils. Acid soils and salt affected soils. Soil pollution. Radiation effect. K. H. Tan, Principles <strong>of</strong> Soil Chemistry, Dekker, New York, 1982. R. A. Home, Chemistry <strong>of</strong> our Environment, Plennum, New York, 1975. CY450 ADVANCED INSTRUMENTAL METHODS OF ANALYSIS (3–0–0) 3 Magnetic Resonance Spectroscopy: NMR. FTNMR. ESR. NQR. X-ray methods: Absorption, Fluorescence, Diffraction. Radiochemical methods. Electron and Ion Spectroscopy. XPS. UPS. EIS. AES. ISS. Photoacoustic Spectroscopy. Basic principles and applications. G. W. Ewing, Instrumental Methods <strong>of</strong> Analysis, McGraw-Hill, New Delhi, 1990. Willard, Merritt, Dean & Settle, Instrumental methods <strong>of</strong> analysis, 6 th Ed., CBS Publishers & Distributors, Delhi, 1986. CY451 CHEMISTRY OF NATURAL PRODUCTS (3–0–0) 3 Alkaloids: Introduction, occurrence, functions, nomenclature, classification, isolation, properties, determination <strong>of</strong> molecular structure. Terpenoids: occurrence, isolation, classification, general --------------------------------------------------------------------- NITK-Course Contents(UG)2010 Page 122 <strong>of</strong> 134
NATIONAL INSTITUTE OF TECHNOLOGY KARNATAKA, SURATHAKAL -----------------------------------------------------------------------------------------------------------------characteristics, structural features, isoprene rule. Steroids and hormones. Natural Pigments. Biosynthesis <strong>of</strong> some natural products: Biosynthesis <strong>of</strong> carbohydrates and photosynthesis, biosynthesis <strong>of</strong> terpenoids and steroids. I. L. Finar, Organic Chemistry, Volume 1: The Fundamental Principles, and Volume 2, Stereochemistry and Chemistry <strong>of</strong> Natural Products, VI Edition, ELBS, 1989. O..P. Agarwal, Chemistry <strong>of</strong> organic natural products, (volumes 1 & 2), Goel Publishing house, Meerut, 1993. CY452 IO-PHYSICAL CHEMISTRY (3–0–0) 3 Molecular species in solution. Energy and equilibria. Enzyme and Enzymatic catalysis � Kinetics and mechanism <strong>of</strong> enzymatic reactions and their specificity. Bioenergetics � Notions <strong>of</strong> TD, application to chemical reactions in living organisms. ATP energetics. C. R. Canter and P. R. Sehimmell, Biophysical Chemistry, Freeman, Sanfransisco. G. M. Barrow, Physical Chemistry <strong>of</strong> Life Sciences, McGraw-Hill, New Delhi. CY453 POLYMERS FOR ELECTRONICS AND OPTOELECTRONICS (3-0-0) 3 Conducting polymers. Electrodepositable resists: Electrodepositable resins formulation. Thermotropic liquid crystal polymers: fundamentals, processing. Photoconductive polymers: charge-carrier generation, charge injection, charge transport and charge trapping; electron-transporting and bipolar polymers. Polymers for optical data storage: Principles <strong>of</strong> optical storage, polymers in recording layer. Nonlinear materials: NLO properties, NLO effects, wave guide devices and thro<strong>ug</strong>h-plane modulators. A. B. Kaiser (Eds. H. Kuzmany, M. Mehring and S. Roth), Electronic properties <strong>of</strong> conj<strong>ug</strong>ated polymers – basic models and applications, Springer-Verlag, Berlin, 1989. Ed. J. A. Chilton & M. T. Goosy, Special polymers for electronics and optoelectronics, Chapman & Hall, 1995. --------------------------------------------------------------------- NITK-Course Contents(UG)2010 Page 123 <strong>of</strong> 134