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Vaporization of JP-8 Jet Fuel in a Simulated Aircraft Fuel Tank ...

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It was shown that the fuel vapor composition as well as the vapor to liquid<br />

volume ratio (V/L) had significant effects on the vapor pressure and the flashpo<strong>in</strong>t [21].<br />

The vapor pressure decreased with <strong>in</strong>creas<strong>in</strong>g sample flashpo<strong>in</strong>t, due to the abundance <strong>of</strong><br />

lighter low molecular weight-high vapor pressure hydrocarbons <strong>in</strong> the low flash po<strong>in</strong>t<br />

samples, while the fuel samples with higher flash po<strong>in</strong>ts had higher concentrations <strong>of</strong><br />

heavy, high molecular weight-low vapor pressure hydrocarbons. For samples with the<br />

same flash po<strong>in</strong>t, decreas<strong>in</strong>g the V/L ratio decreased the vapor pressure, due to the<br />

depletion <strong>of</strong> high vapor pressure hydrocarbons at the low V/L ratio. The significance <strong>of</strong><br />

these f<strong>in</strong>d<strong>in</strong>gs is that the variation <strong>of</strong> flash po<strong>in</strong>t among samples <strong>of</strong> <strong>Jet</strong>-A reflects the<br />

relative concentration between high and low vapor pressure components which control<br />

the low temperature vaporization processes typically seen <strong>in</strong> a fuel tank.<br />

The fuel used <strong>in</strong> this experimentation was tested for flashpo<strong>in</strong>t <strong>in</strong> order to<br />

determ<strong>in</strong>e which <strong>of</strong> the characterized fuels [21] would be best suited for model<strong>in</strong>g the<br />

experiments. The experimental fuel had a measured flashpo<strong>in</strong>t <strong>of</strong> 117°F, therefore, the<br />

two fuel compositions from ref. 21 chosen to “bracket” the fuel composition used <strong>in</strong> the<br />

present experiments were the fuels with flashpo<strong>in</strong>ts <strong>of</strong> 115°F and 120°F. Figure 2.1<br />

shows the distribution <strong>of</strong> n-alkane species by number <strong>of</strong> carbon atoms <strong>in</strong> the two fuel<br />

compositions chosen from ref. 21. It is apparent that the 115 °F flashpo<strong>in</strong>t fuel has a<br />

higher concentration <strong>of</strong> low molecular weight-low boil<strong>in</strong>g po<strong>in</strong>t species than the 120°F<br />

flashpo<strong>in</strong>t fuel, which has a broader range over the high molecular weight-high boil<strong>in</strong>g<br />

po<strong>in</strong>t species. This figure helps to visualize the fact that fuels with higher concentrations<br />

<strong>of</strong> light components will have lower flashpo<strong>in</strong>ts and be more flammable than fuels with<br />

higher concentrations <strong>of</strong> heavy components.<br />

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