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Vaporization of JP-8 Jet Fuel in a Simulated Aircraft Fuel Tank ...

Vaporization of JP-8 Jet Fuel in a Simulated Aircraft Fuel Tank ...

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the tank and the ullage vapor concentration was vary<strong>in</strong>g very little with time. This quasi-<br />

equilibrium was critical to the calculations, as it was necessary to have a start<strong>in</strong>g<br />

condition where the ullage vapor concentration was nearly steady, known, and could be<br />

determ<strong>in</strong>ed with equilibrium calculations. Subsequent time-march<strong>in</strong>g calculations<br />

<strong>in</strong>itiated with the equilibrium calculation, so it was imperative to have a correct<br />

assessment <strong>of</strong> the equilibrium condition. The system was considered steady if the ullage<br />

vapor concentration varied by less than 1,000 ppm or 0.1% over a period <strong>of</strong> ten m<strong>in</strong>utes.<br />

At this quasi-equilibrium stage, the mass balance dictates that the rate <strong>of</strong> fuel vaporiz<strong>in</strong>g<br />

is equal to the rate <strong>of</strong> fuel condens<strong>in</strong>g, and the amount <strong>of</strong> fuel <strong>in</strong> the ullage is constant.<br />

In order to obta<strong>in</strong> accurate read<strong>in</strong>gs with the FID hydrocarbon analyzer, a lengthy<br />

warm-up procedure is recommended by the manufacturer. S<strong>in</strong>ce the warm-up typically<br />

takes about 4 or 5 hours, the analyzer was usually turned on Monday morn<strong>in</strong>g and<br />

allowed to run until the end <strong>of</strong> the week. The warm up procedure started with turn<strong>in</strong>g on<br />

the burner oven heater and allow<strong>in</strong>g the temperature to stabilize at 190°C for one hour.<br />

At this po<strong>in</strong>t the sample pump was switched on and allowed to run for 30-45 m<strong>in</strong>utes,<br />

after which time the flame could be lit by purg<strong>in</strong>g the fuel and sample l<strong>in</strong>es for 1 m<strong>in</strong>ute,<br />

then press<strong>in</strong>g the igniter button. After the burner was lit, a stabilization time <strong>of</strong> 2-3 hours<br />

was required before the analyzer would be accurate. Hydrocarbon-free “zero” air or<br />

nitrogen (whichever was available) was passed through the analyzer for about 15 m<strong>in</strong>utes<br />

to set the zero hydrocarbon concentration, then the 2% propane was passed through to set<br />

20,000 ppm. L<strong>in</strong>earity was checked by pass<strong>in</strong>g through 4% propane to see if the analyzer<br />

read 40,000 ppm. This l<strong>in</strong>earity check allowed for a hydrocarbon concentration range<br />

accurate from 0 to 40,000 ppm, which was enough for most <strong>of</strong> the test<strong>in</strong>g <strong>in</strong>volved.<br />

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