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TPF-I SWG Report - Exoplanet Exploration Program - NASA

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C HAPTER 2<br />

Figure 2-3. Simulated mid-infrared spectrum of an Earth-like planet showing the<br />

effects of viewing angle (Giovanna Tinetti, Institut d’Astrophysique de Paris).<br />

2.4.1 Biomarker Signatures in the Mid Infrared<br />

In the mid-IR, the classical signature of biological activity is the combined detection of the 9.6-μm O 3<br />

band, the 15-μm CO 2 band, and the 6.3-μm H 2 O band or its rotational band that extends from 12 μm out<br />

into the microwave region (Selsis and Despois 2002). Because oxygen is a chemically reactive gas, it<br />

follows that reduced gases and oxygen have to be produced concurrently to be detectable in the<br />

atmosphere, as they react rapidly with each other. The oxygen and ozone absorption features in the visible<br />

and thermal infrared, respectively, could indicate the presence of photosynthetic biological activity on<br />

Earth any time during the past 50% of the age of the Solar System. In the Earth’s atmosphere, the 9.6-μm<br />

O 3 band is a poor quantitative indicator of the O 2 amount, but an excellent qualitative indicator for the<br />

existence of even traces of O 2 . The Ozone 9.6-μm band is a very nonlinear indicator of O 2 for two<br />

reasons. First, for the present atmosphere, low-resolution spectra of this band show little change with the<br />

O 3 abundance because it is strongly saturated. Second, the apparent depth of this band remains nearly<br />

constant as O 2 increases from 0.01 times the present atmosphere level (PAL) of O 2 to 1 PAL (Segura et al.<br />

2003). The primary reason for this is that the stratospheric ozone increases that accompanied the O 2<br />

buildup lead to additional ultraviolet heating of the stratosphere. At these higher temperatures, the<br />

stratospheric emission from this band partially masks the absorption of upwelling thermal radiation from<br />

the surface.<br />

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