UNDERSTANDING VARIATION IN PARTITION COEFFICIENT, Kd ...

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Table D.8. Freundlich equations identified in literature for cesium. a 1 b 1 Range of Solution Cs Concentration (M) D.13 Experimental Ref. 2 1.7 0.677 Water/Batcombe Sediment 1 3,300 0.909 Water/Denchworth Sediment 1 260 0.841 Water/Tedburn Sediment 1 16 0.749 Water/Teigngrace Sediment 1 12.2 0.745 1x10 -8 to 1x10 -12 Water/Batcombe Sediment 1 6,070 0.899 1x10 -8 to 1x10 -12 Water/Denchworth Sediment 1 1,290 0.849 1x10 -8 to 1x10 -12 163 0.815 1x10 -8 to 1x10 -12 1.23 0.657 1x10 -8 to 1x10 -12 Water/Tedburn Sediment 1 Water/Teigngrace Sediment 1 CaCl 2/Batcombe Sediment 1 0.63 0.659 CaCl 2/Batcombe Sediment 1 427 0.814 1x10 -8 to 1x10 -12 CaCl 2/Denchworth Sediment 1 1.5 0.599 CaCl 2/Denchworth Sediment 1 48.1 0.754 1x10 -8 to 1x10 -12 CaCl 2/Tedburn Sediment 1 17 0.739 CaCl 2/Tedburn Sediment 1 5.22 0.702 1x10 -8 to 1x10 -12 CaCl 2/Teigngrace Sediment 1 4.4 0.716 CaCl 2/Teigngrace Sediment 1 0.22 1.1 1x10 -9 to 1.5x10 -2 0.017 0.53 1x10 -9 to 1.5x10 -2 0.13 1 1x10 -9 to 1.5x10 -2 0.048 0.67 1x10 -9 to 1.5x10 -2 5.10x10 -4 3.00x10 -3 1.30x10 -5 0.21 1x10 -9 to 1.5x10 -2 0.48 1x10 -9 to 1.5x10 -2 0.013 1x10 -9 to 1.5x10 -2 Bentonite/Water 2 Bentonite/Water 2 Bentonite/Groundwater 2 Bentonite/Groundwater 2 Takadata Loam/Water 2 Takadata Loam/Groundwater 2 Hachinohe Loam/Water 2 2.30x10 -5 0.38 1x10 -9 to 1.5x10 -2 Hachinohe Loam/Groundwater 2
a 1 b 1 Range of Solution Cs Concentration (M) D.14 Experimental Ref. 2 2.70x10 -4 0.546 1x10 -8 to 1x10 -2 Unwashed/Kaolinite/pH 2 3 5.20x10 -4 0.543 1x10 -8 to 1x10 -2 Unwashed/Kaolinite/pH 4 3 2.04x10 -3 0.588 1x10 -8 to 1x10 -2 Unwashed/Kaolinite/pH 10 3 2.27x10 -3 0.586 1x10 -8 to 1x10 -2 Sodium/Kaolinite/pH 2 3 5.04x10 -2 0.723 1x10 -8 to 1x10 -2 Sodium/Kaolinite/pH 4 3 3.49x10 -2 0.703 1x10 -8 to 1x10 -2 Na/Kaolinite/pH 7 3 0.235 0.821 1x10 -8 to 1x10 -2 Na/Kaolinite/pH 10 3 3.03x10 -2 0.804 1x10 -8 to 1x10 -2 0.135 0.845 1x10 -8 to 1x10 -2 0.247 0.881 1x10 -8 to 1x10 -2 8.71x10 -3 1.02x10 -4 1.05x10 -2 3.17x10 -2 0.694 1x10 -8 to 1x10 -2 0.503 1x10 -8 to 1x10 -2 0.709 1x10 -8 to 1x10 -2 0.755 1x10 -8 to 1x10 -2 0.224 0.815 1x10 -8 to 1x10 -2 0.241 0.839 1x10 -8 to 1x10 -2 0.481 0.897 1x10 -8 to 1x10 -2 1.84 0.938 1x10 -8 to 1x10 -2 0.274 0.82 1x10 -8 to 1x10 -2 3.40x10 -2 4.90x10 -2 4.00x10 -2 0.51 1x10 -7 to 1x10 -3 0.5 1x10 -7 to 1x10 -3 Ca/Kaolinite/pH 2 3 Ca/Kaolinite/pH 4 3 Ca/Kaolinite/pH 7 3 Ca/Kaolinite/pH 10 3 Na/Montmorillonite/pH 2 3 Na/Montmorillonite/pH 4 3 Na/Montmorillonite./pH 7 3 Na/Montmorillonite/pH 10 3 Ca/Montmorillonite/pH 2 3 Ca/Montmorillonite/pH 4 3 Ca/Montmorillonite/pH 7 3 Ca/Montmorillonite/pH 10 3 Granite/pH 8.2 4 Granite/pH 8.2 4 0.5 5 1 Parameters “a” and “b” are fitting parameters in the Freundlich equation. 2 References: 1 = Fukui, 1990; 2 = Konishi et al., 1988; 3 = Adeleye et al., 1994; 4 = Serne et al., 1993; 5 = Shiao et al., 1979.
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United States Office of Air and Rad
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NOTICE The following two-volume rep
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This publication is the result of a
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TO COMMENT ON THIS GUIDE OR PROVIDE
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CONTENTS NOTICE ...................
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Concentrations Extractable Iron Con
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Appendix A - Acronyms and Abbreviat
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Figure E.1. Variation of K d for Cr
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Table 5.16. Uranium(VI) aqueous spe
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Table H.3. Simple and multiple regr
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1.0 Introduction The objective of t
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discussed. The geochemical modeling
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2.0 The K d Model The simplest and
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track many more parameters and some
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of interest. The retardation factor
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(e.g., soil). An increasing body of
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complexation constants for the cont
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the soil column. Additionally, the
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Element Table 5.2. Concentrations o
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5.2.3 Aqueous Speciation Cadmium fo
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5.2.4 Dissolution/Precipitation/Cop
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cadmium, indicating that cadmium an
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5.2.6.2.2 Limits of K d Values with
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organic chelates (e.g., EDTA). Init
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(tarapacaite) in chromium sludge fr
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K d). Soils containing Mn oxides ox
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Table 5.7. Estimated range of Kd va
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most common valence state of lead e
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Table 5.8. Lead aqueous species inc
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Under reducing conditions, galena (
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C Adsorption of lead increases with
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(Choppin, 1983). Plutonium hydrolyt
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Table 5.10. Plutonium aqueous speci
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5.6.5 Sorption/Desorption Plutonium
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content in the system. Additionally
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much greater concentrations. Thus,
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exchanged which they attributed to
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up tables was based in part on thei
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organic complexes likely predominat
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Thorium undergoes hydrolysis in aqu
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The distribution of thorium aqueous
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from about 10 -8.5 mol/l (0.0007 mg
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Based on the assumptions and limita
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5.10 Tritium Geochemistry And K d V
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uranium. Uranium(VI) species domina
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gives 0.1 to 10 µg/l as the range
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mineral in reducing ore zones (Fron
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Percent Distribution 100 80 60 40 2
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5.11.6 Partition Coefficient, K d ,
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No attempt was made to statisticall
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Table 5.18. Selected chemical and t
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Another objective of this report is
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6.0 REFERENCES Adriano, D. C. 1992.
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Bensen, D. W. 1960. Review of Soil
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Metals by Geomedia. Variables, Mech
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EPA (U.S. Environmental Protection
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Griffin, R. A., A. K. Au, and R. R.
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+ Keeney-Kennicutt, W. L., and J. W
Page 127 and 128: Mattigod, S. V., A. L. Page, and I.
Page 129 and 130: Oscarson, D. W., and H. B. Hume. 19
Page 131 and 132: Relyea, J. F. and D. A. Brown. 1978
Page 133 and 134: Schultz, R. K., R. Overstreet, and
Page 135 and 136: Szalay, A. 1964. “Cation Exchange
Page 137 and 138: Yariv, S., and H. Cross. 1979. Geoc
Page 139 and 140: APPENDIX A Acronyms, Abbreviations,
Page 141 and 142: PC Personal computers operating und
Page 143 and 144: A.3.0 List of Symbols and Notation
Page 145 and 146: APPENDIX B Definitions
Page 147 and 148: Clay Content - particle size fracti
Page 149 and 150: Polynuclear Species - an aqueous sp
Page 151 and 152: C.1.0 Background Appendix C Partiti
Page 153 and 154: Cadmium K d Table C.2. Correlation
Page 155 and 156: C.3.0 Data Set for Soils Table C.4
Page 157 and 158: Cd K d (ml/g) Clay Cont. (wt%) pH C
Page 167 and 168: D.1.0 Background Appendix D Partiti
Page 169 and 170: A second data set (see Section D.4)
Page 171 and 172: Table D.3. Correlation coefficients
Page 173 and 174: By transposing the CEC and cesium K
Page 175 and 176: Table D.6. Cesium K d values measur
Page 177: eported in Table D.8 are described
Page 181 and 182: Figure D.4. Generalized cesium Freu
Page 183 and 184: Table D.10. Estimated range of K d
Page 185 and 186: D.3.0 K d Data Set for Soils and Pu
Page 187 and 188: Cesium Kd (ml/g) Clay (wt.% ) Mica
Page 193 and 194: Cesium K d (ml/g) Clay (wt%) Mica (
Page 195 and 196: Bruggenwert, M. G. M., and A. Kamph
Page 197 and 198: Shiao, S. Y., P. Rafferty, R. E. Me
Page 199 and 200: E.1.0 Background Appendix E Partiti
Page 201 and 202: chromium-reductive soils may stem f
Page 204 and 205: E.2.0 Approach The approach used to
Page 206 and 207: Table E.3. Estimated range of K d v
Page 208 and 209: Table E.4. Data from Rai et al. (19
Page 210 and 211: E.4.0 References Davis, J. A. and J
Page 212 and 213: APPENDIX F Partition Coefficients F
Page 214 and 215: (CEC) of the soils. Such an anomaly
Page 216 and 217: Table F.1. Summary of K d values fo
Page 218 and 219: Figure F.2. Variation of K d as a f
Page 220 and 221: F.4.0 References Abd-Elfattah, A.,
Page 222 and 223: APPENDIX G Partition Coefficients F
Page 224 and 225: A number of investigators have exam
Page 226 and 227: pH value, which is typical of the m
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These significant reductions in ads
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This is typically accomplished by t
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The scatterplots are typically disp
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Table G.2. Regression models for pl
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G.4.0 References Barney, G. S. 1984
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Nelson, D. M., R. P. Larson, and W.
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APPENDIX H Partition Coefficients F
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1.6 ml/g for a measurement made on
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Figure H.1. Relation between stront
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Figure H.2. Relation between stront
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H.2.4 Approach Figure H.4. Relation
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A second look-up table (Table H.5)
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Sr K d (ml/g) Clay Content (%) pH C
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Sr K d (ml/g) Clay Content (%) pH C
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Sr K d (ml/g) Clay Conten t (%) pH
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Konishi, M., K. Yamamoto, T. Yanagi
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APPENDIX I Partition Coefficients F
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descriptive statistics of the thori
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Figure I.1. Linear regression betwe
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The look-up table (Table I.5) for t
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Thorium K d (ml/g) pH Clay (wt.%) C
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Rai, D., A. R. Felmy, D. A. Moore,
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J.1.0 Background Appendix J Partiti
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J.2.2 Uranium K d Studies on Soils
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Washington. The studies included an
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and then decreases with increasing
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Kd (ml/g) 100,000 10,000 1,000 100
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papers. Warnecke et al. (1984) indi
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Anderson et al. (1982) summarize an
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McKinley and Scholtis (1993) compar
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In a similar comparison of sorption
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J.3.1 K d Values as a Function ff p
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discussed, and one would have to ma
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al., 1992; and others). These refer
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· Manskaya et al. (1956) studied a
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concentrations of humic acid, there
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pH U Kd (ml/g) Clay Cont. (wt.%) CE
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J.6.0 References Ames, L. L., J. E.
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Erikson, R. L., C. J. Hostetler, R.
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R. C. Ewing. Materials Research Soc
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Sheppard, M. I., and D. H. Thibault
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Yamamoto, T., E. Yunoki, M. Yamakaw
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UNDERSTANDING VARIATION IN PARTITION COEFFICIENT, Kd ...

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