UNDERSTANDING VARIATION IN PARTITION COEFFICIENT, Kd ...

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Sr K d (ml/g) Clay Content (%) pH CEC (meq/ 100 g) Surface Area (m 2 /g) [Ca] ppm [Sr] Background Solution 135 26.9 8.3 13.6 0 Water Bowdoin Soil H.15 Soil ID Reference 1 , Comments 8, soil from Montana 600 33.5 6.5 26.3 0 Water Hall soil 8, soil from Nebraska 70 3.5 8.3 5.8 0 Water Composite Soil 8, soil from Hanford Site, Richland, Washington 1 References: 1 = Ohnuki, 1994, 2 = Patterson and Spoel, 1981; 3 = Keren and O'Connor, 1983; 4 = Rhodes and Nelson, 1957; 5 = Serne et al., 1993; 6 = Vine et al., 1980; 7 = Lieser and Steinkopff, 1989; 8 = McHenry, 1958
H.4.0 K d Data Set for Pure Mineral Phases and Soils Table H.8 lists the available K d values identified for experiments conducted with pure mineral phases as well as soils. The K d values are listed with ancillary parameters that included clay content, pH, CEC, surface area, solution calcium concentrations, and solution strontium concentrations. Sr K d (ml/g) Clay Conten t (%) Table H.8. Strontium K d data set for pure mineral phases and soils. pH CEC (meq/ 100 g) Surface Area (m 2 /g) [Ca] (ppm) H.16 [Sr] Background Solution Soil ID Reference 1 and Comments 21 0.8 5.2 0.9 1.4 0 * NaClO 4 Soil A 1, Ohnuki, 1994 19 0.8 5.6 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 22 0.8 6.2 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 26 0.8 6.45 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 24 0.8 6.6 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 30 0.8 8.4 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 43 0.8 9.2 0.9 1.4 0 * NaClO 4 Soil A 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 0 5.5 * Quartz 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 290 5.5 3.3 26.4 0 * Kaolinite 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 140 5.5 3.6 43.9 0 * Halloysite 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 17 5.5 0.6 1.4 0 * Chlorite 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 37 5.5 1.9 2.2 0 * Sericite 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 8 5.5 0.5 0.7 0 * Oligoclase 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2 6 5.5 0.5 0 * Hornblend 1, * = 4.4x10 2 Bq/ml 85- Sr in 2.4x10 -8 M SrCl 2
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United States Office of Air and Rad
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NOTICE The following two-volume rep
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This publication is the result of a
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TO COMMENT ON THIS GUIDE OR PROVIDE
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CONTENTS NOTICE ...................
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Concentrations Extractable Iron Con
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Appendix A - Acronyms and Abbreviat
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Figure E.1. Variation of K d for Cr
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Table 5.16. Uranium(VI) aqueous spe
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Table H.3. Simple and multiple regr
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1.0 Introduction The objective of t
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discussed. The geochemical modeling
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2.0 The K d Model The simplest and
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track many more parameters and some
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of interest. The retardation factor
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(e.g., soil). An increasing body of
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complexation constants for the cont
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the soil column. Additionally, the
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Element Table 5.2. Concentrations o
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5.2.3 Aqueous Speciation Cadmium fo
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5.2.4 Dissolution/Precipitation/Cop
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cadmium, indicating that cadmium an
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5.2.6.2.2 Limits of K d Values with
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organic chelates (e.g., EDTA). Init
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(tarapacaite) in chromium sludge fr
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K d). Soils containing Mn oxides ox
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Table 5.7. Estimated range of Kd va
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most common valence state of lead e
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Table 5.8. Lead aqueous species inc
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Under reducing conditions, galena (
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C Adsorption of lead increases with
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(Choppin, 1983). Plutonium hydrolyt
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Table 5.10. Plutonium aqueous speci
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5.6.5 Sorption/Desorption Plutonium
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content in the system. Additionally
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much greater concentrations. Thus,
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exchanged which they attributed to
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up tables was based in part on thei
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organic complexes likely predominat
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Thorium undergoes hydrolysis in aqu
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The distribution of thorium aqueous
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from about 10 -8.5 mol/l (0.0007 mg
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Based on the assumptions and limita
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5.10 Tritium Geochemistry And K d V
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uranium. Uranium(VI) species domina
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gives 0.1 to 10 µg/l as the range
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mineral in reducing ore zones (Fron
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Percent Distribution 100 80 60 40 2
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5.11.6 Partition Coefficient, K d ,
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No attempt was made to statisticall
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Table 5.18. Selected chemical and t
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Another objective of this report is
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6.0 REFERENCES Adriano, D. C. 1992.
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Bensen, D. W. 1960. Review of Soil
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Metals by Geomedia. Variables, Mech
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EPA (U.S. Environmental Protection
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Griffin, R. A., A. K. Au, and R. R.
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+ Keeney-Kennicutt, W. L., and J. W
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Mattigod, S. V., A. L. Page, and I.
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Oscarson, D. W., and H. B. Hume. 19
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Relyea, J. F. and D. A. Brown. 1978
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Schultz, R. K., R. Overstreet, and
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Szalay, A. 1964. “Cation Exchange
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Yariv, S., and H. Cross. 1979. Geoc
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APPENDIX A Acronyms, Abbreviations,
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PC Personal computers operating und
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A.3.0 List of Symbols and Notation
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APPENDIX B Definitions
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Clay Content - particle size fracti
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Polynuclear Species - an aqueous sp
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C.1.0 Background Appendix C Partiti
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Cadmium K d Table C.2. Correlation
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C.3.0 Data Set for Soils Table C.4
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Cd K d (ml/g) Clay Cont. (wt%) pH C
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D.1.0 Background Appendix D Partiti
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A second data set (see Section D.4)
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Table D.3. Correlation coefficients
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By transposing the CEC and cesium K
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Table D.6. Cesium K d values measur
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eported in Table D.8 are described
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a 1 b 1 Range of Solution Cs Concen
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Figure D.4. Generalized cesium Freu
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Table D.10. Estimated range of K d
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D.3.0 K d Data Set for Soils and Pu
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Cesium Kd (ml/g) Clay (wt.% ) Mica
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Cesium K d (ml/g) Clay (wt%) Mica (
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Bruggenwert, M. G. M., and A. Kamph
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Shiao, S. Y., P. Rafferty, R. E. Me
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E.1.0 Background Appendix E Partiti
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chromium-reductive soils may stem f
Page 204 and 205: E.2.0 Approach The approach used to
Page 206 and 207: Table E.3. Estimated range of K d v
Page 208 and 209: Table E.4. Data from Rai et al. (19
Page 210 and 211: E.4.0 References Davis, J. A. and J
Page 212 and 213: APPENDIX F Partition Coefficients F
Page 214 and 215: (CEC) of the soils. Such an anomaly
Page 216 and 217: Table F.1. Summary of K d values fo
Page 218 and 219: Figure F.2. Variation of K d as a f
Page 220 and 221: F.4.0 References Abd-Elfattah, A.,
Page 222 and 223: APPENDIX G Partition Coefficients F
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Page 228 and 229: These significant reductions in ads
Page 230 and 231: This is typically accomplished by t
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Page 234 and 235: Table G.2. Regression models for pl
Page 236 and 237: G.4.0 References Barney, G. S. 1984
Page 238 and 239: Nelson, D. M., R. P. Larson, and W.
Page 240 and 241: APPENDIX H Partition Coefficients F
Page 242 and 243: 1.6 ml/g for a measurement made on
Page 244 and 245: Figure H.1. Relation between stront
Page 246 and 247: Figure H.2. Relation between stront
Page 248 and 249: H.2.4 Approach Figure H.4. Relation
Page 250 and 251: A second look-up table (Table H.5)
Page 252 and 253: Sr K d (ml/g) Clay Content (%) pH C
Page 256 and 257: Sr K d (ml/g) Clay Conten t (%) pH
Page 264 and 265: Konishi, M., K. Yamamoto, T. Yanagi
Page 266 and 267: APPENDIX I Partition Coefficients F
Page 268 and 269: descriptive statistics of the thori
Page 270 and 271: Figure I.1. Linear regression betwe
Page 272 and 273: The look-up table (Table I.5) for t
Page 274 and 275: Thorium K d (ml/g) pH Clay (wt.%) C
Page 276 and 277: Rai, D., A. R. Felmy, D. A. Moore,
Page 278 and 279: J.1.0 Background Appendix J Partiti
Page 280 and 281: J.2.2 Uranium K d Studies on Soils
Page 282 and 283: Washington. The studies included an
Page 284 and 285: and then decreases with increasing
Page 286 and 287: Kd (ml/g) 100,000 10,000 1,000 100
Page 288 and 289: papers. Warnecke et al. (1984) indi
Page 290 and 291: Anderson et al. (1982) summarize an
Page 292 and 293: McKinley and Scholtis (1993) compar
Page 294 and 295: In a similar comparison of sorption
Page 296 and 297: J.3.1 K d Values as a Function ff p
Page 298 and 299: discussed, and one would have to ma
Page 300 and 301: al., 1992; and others). These refer
Page 302 and 303: · Manskaya et al. (1956) studied a
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concentrations of humic acid, there
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pH U Kd (ml/g) Clay Cont. (wt.%) CE
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J.6.0 References Ames, L. L., J. E.
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Erikson, R. L., C. J. Hostetler, R.
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R. C. Ewing. Materials Research Soc
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Sheppard, M. I., and D. H. Thibault
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Yamamoto, T., E. Yunoki, M. Yamakaw
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