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Extraction Technologies For Medicinal And Aromatic Plants - Unido

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EXTRACTION TECHNOLOGIES FOR MEDICINAL AND AROMATIC PLANTS<br />

desorption (using injector glass liners packed with Tenax-TA as adsorbent<br />

traps for aroma collection at ambient room temperature) and desorption at<br />

the interior of a GC injector. This DHS-type protocol was used to characterize<br />

fresh tomato fl avor compounds; the results were compared with published<br />

data from a static headspace method (Table 1).<br />

Table 1: Concentration of selected tomato aromas from heat-processed tomato<br />

juice by static headspace trapping (SHT) and dynamic headspace trapping (DHT),<br />

expressed in parts per billion (ppb)<br />

Compound SHT, ppb DHT, ppb<br />

(E)-2-hexanal 5 340<br />

1-Penten-3-one 61 100<br />

2-Isobutylthiazole 2 450<br />

2-Methylfuran 97 1,060<br />

2-Pentylfuran 26 700<br />

3-Methybutanal 17 750<br />

3-Methylfuran 717 3,200<br />

6-Methyl-5-hepten-2-one 21 1,330<br />

Acetone 325 -<br />

Benzaldehyde 3 30<br />

Dimethyl disulfi de 16 630<br />

Dimethyl sulfi de 5,205 2,974<br />

Ethanol 311 -<br />

Geranial 2 130<br />

Hexanal 188 6,210<br />

Pentanal 48 470<br />

In the present study, this DHT-type protocol was used to characterize<br />

fresh tomato fl avour compounds for comparison with related literature<br />

methods.<br />

9.7.4 Some Practical Examples of Headspace Technique<br />

Use<br />

9.7.4.1 Tomato Juice<br />

Fresh tomato juice was made from vine-ripe fruit by Campbell<br />

Soup Company’s R&D centre in Davis, USA. Chemicals were reagent grade,<br />

supplied from reliable sources.<br />

165

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