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Physics for Geologists, Second edition

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50 Optics<br />

called Iceland Spar. Two slices of Iceland Spar, cut normal to the optic axis,<br />

are cemented with Canada balsam. The incident light on the prism gives rise<br />

to two refracted rays, one of which is totally reflected by the balsam, the other<br />

transmitted. The transmitted ray is polarized. In a petrological microscope,<br />

one nicol prism is used to polarize the light (the polarizer), another is used to<br />

analyse it (the analyser). In modern petrological microscopes, the nicol prism<br />

has been replaced by polars that are made of polaroidTM, but the effect is<br />

the same.<br />

Optical activity<br />

Some substances have the ability to rotate the plane of polarization of light<br />

passing through them. This is called optical activity. These substances, usu-<br />

ally natural organic substances, have asymmetric molecules. Crude oil is such<br />

a substance, and it is a strong argument <strong>for</strong> the organic origin of petroleum.<br />

Pleochroism, dichroism and trichroism<br />

Minerals in thin section that change colour, either hue or intensity, when<br />

rotated on a stage in polarized light are called pleochroic and the process is<br />

called pleochroism. Minerals with only one optic axis (those belonging to the<br />

hexagonal and tetragonal systems) show two characteristic colours. Those<br />

with two optic axes - the biaxial minerals, which belong to the orthorhom-<br />

bic, monoclinic and anorthic systems - show three characteristic colours.<br />

Isotropic minerals are not pleochroic because the absorption of light is equal<br />

in all directions. Changes of colour or hue are due to unequal absorption of<br />

light of different frequencies (or wavelengths) in different orientations; and<br />

changes in intensity are due to loss of amplitude in different orientations.<br />

Tourmaline (hexagonal, trigonal) is a uniaxial mineral, and we have seen<br />

that no polarized light is transmitted through crystals cut parallel to the<br />

optic axis when its axis is at 90° to the direction of polarization. In other<br />

orientations light is partly absorbed. Basal sections of uniaxial minerals<br />

do not show pleochroism because absorption of light of all wavelengths<br />

is equal in all directions. Pleochroic haloes, due to small inclusions of<br />

a radioactive contaminant, are common in tourmaline. Biotite (monoclinic,<br />

pseudo-hexagonal; biaxial) is a common pleochroic mineral. In sections<br />

other than basal, its colour changes from a dark brown, when the cleavage<br />

is parallel to the plane of polarization, to yellow.<br />

Specialists may use the term dichroism <strong>for</strong> uniaxial minerals, because<br />

these show two characteristic colours. Similarly, trichroism may be used<br />

<strong>for</strong> biaxial minerals, which show three characteristic colours.<br />

Birefringence<br />

Anisotropic crystals are found to have one index of refraction <strong>for</strong> light lin-<br />

early polarized in one direction, and another <strong>for</strong> light linearly polarized in<br />

Copyright 2002 by Richard E. Chapman

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