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CH1-silicon wafer & Si epitaxy - KTH

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2B1242 SPRING 2006<br />

<strong>Si</strong> epi-growth rate for Cl-based chemistry<br />

Either deposition or etching depending on T, P or concentration (mole<br />

Fraction)<br />

Reaction is complex, e.g. <strong>Si</strong>Cl 4 :<br />

<strong>Si</strong>Cl 4 + H 2 ⇔ <strong>Si</strong>HCl 3 + HCl <strong>Si</strong>HCl 3 ⇔ <strong>Si</strong>Cl 2 + HCl<br />

<strong>Si</strong>HCl 3 + H 2 ⇔ <strong>Si</strong>H 2 Cl 2 + HCl <strong>Si</strong>Cl 2 + H 2 ⇔ <strong>Si</strong> + 2HCl<br />

<strong>Si</strong>H 2 Cl 2 ⇔ <strong>Si</strong>Cl 2 + H 2<br />

Mikael Östling <strong>KTH</strong>

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