Enamels and enamelling; an introduction to the preparation and ...
Enamels and enamelling; an introduction to the preparation and ...
Enamels and enamelling; an introduction to the preparation and ...
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90 ENAMELS AND ENAMELLING.<br />
in this respect is <strong>the</strong> ash of certain lignites, which, in addition-<br />
<strong>to</strong> carbon, contains a considerable qu<strong>an</strong>tity of ferric oxide<br />
capable of colouring<br />
<strong>the</strong> enamel mass.<br />
Where <strong>the</strong> draught in <strong>the</strong> enamel smelting furnace is<br />
defective, <strong>the</strong> products of combustion are likely <strong>to</strong> be highly<br />
charged with reducing gases, which will have <strong>an</strong> injurious<br />
effect on m<strong>an</strong>y coloured enamels ; for inst<strong>an</strong>ce, <strong>the</strong> emerald<br />
green shade produced by cupric oxide will, under such con-<br />
ditions, be invariably discoloured owing <strong>to</strong> <strong>the</strong> reduction of<br />
<strong>the</strong> cupric oxide <strong>to</strong> cuprous oxide.<br />
Consequently, care must be taken <strong>to</strong> select a fuel that yields<br />
no flying ash, <strong><strong>an</strong>d</strong> <strong>to</strong> construct <strong>the</strong> furnace in such a m<strong>an</strong>ner<br />
as <strong>to</strong> ensure <strong>an</strong> efficient draught in order that <strong>the</strong> fuel may<br />
be completely consumed <strong>to</strong> carbon dioxide <strong><strong>an</strong>d</strong> water vapour.<br />
The fuel at <strong>the</strong> disposal of <strong>the</strong> enamel-maker includes<br />
wood, peat, lignite, coal, wood charcoal, coke, <strong><strong>an</strong>d</strong>,<br />
in some<br />
places, <strong>an</strong>thracite.<br />
Under ordinary circumst<strong>an</strong>ces wood is <strong>to</strong>o expensive for<br />
use as fuel in smelting enamels, <strong><strong>an</strong>d</strong> is moreover attended<br />
with <strong>the</strong> inconvenience that it burns away very quickly, so<br />
that <strong>the</strong> fire requires frequent attention <strong>to</strong> keep it up.<br />
Peat is of low calorific value, yields a large proportion of<br />
ash, <strong><strong>an</strong>d</strong> is difficult <strong>to</strong> use in furnaces on account of its bulky<br />
nature.<br />
Wood charcoal, especially from hard woods such as beech,<br />
forms <strong>an</strong> excellent fuel in every respect, <strong>the</strong> ash being small,<br />
<strong>the</strong> combustion perfect, <strong><strong>an</strong>d</strong> <strong>the</strong> heating power considerable.<br />
Unfortunately in most places it is <strong>to</strong>o expensive for our purpose,<br />
<strong><strong>an</strong>d</strong> it is only where wood is abund<strong>an</strong>t that <strong>the</strong> use of<br />
charcoal is feasible. By reason of its high content of potassium<br />
carbonate, <strong>the</strong> ash from wood or charcoal c<strong>an</strong> be utilised as a<br />
source of potash for <strong>the</strong> <strong>preparation</strong> of common enamels.<br />
When lignite is used <strong>the</strong> dense, dark-coloured kinds should<br />
be chosen, as <strong>the</strong>se alone have a suitable calorific power, <strong>the</strong><br />
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