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Enamels and enamelling; an introduction to the preparation and ...

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62 ENAMELS AND ENAMELLING.<br />

<strong><strong>an</strong>d</strong> yellow-forming pigments <strong>to</strong>ge<strong>the</strong>r in suitable proportions'.<br />

Success is, however, certain only when a <strong>preparation</strong> of<br />

<strong>an</strong>timony is used along with <strong>the</strong> red iron pigment (ferric<br />

aluminate) ; gold compounds are unsuitable, being <strong>to</strong>o readily<br />

converted in<strong>to</strong> metallic gold.<br />

The resulting shade of or<strong>an</strong>ge obtained varies from or<strong>an</strong>ge<br />

yellow, when <strong>the</strong> <strong>an</strong>timony <strong>preparation</strong> preponderates, <strong>to</strong> a<br />

redder tinge when <strong>the</strong> conditions are reversed.<br />

GREEN PIGMENTS.<br />

Green enamel may be prepared in various ways :<br />

by<br />

in-<br />

corporating certain metallic oxides with <strong>the</strong> enamel mass, or<br />

by adding <strong>to</strong> <strong>the</strong> latter a mixture of pigments producing blue<br />

<strong><strong>an</strong>d</strong> yellow colours respectively. As, however, in this latter<br />

method <strong>the</strong> resulting shade of colour is less under control,<br />

besides being more troublesome, <strong>the</strong> direct process is generally<br />

adopted.<br />

The oxides capable of colouring enamels green, are, ferrous<br />

oxide, cupric oxide <strong><strong>an</strong>d</strong> chromic oxide. Each of <strong>the</strong>se develops<br />

its own particular shade of green, ferrous oxide yielding " bottle<br />

green" (<strong>the</strong> colour of common green glass), whilst copper <strong><strong>an</strong>d</strong><br />

chromium furnish emerald shades of different kinds readily<br />

distinguishable by comparing glasses tinted with <strong>the</strong>se oxides.<br />

Ferrous Oxide.<br />

Owing <strong>to</strong> <strong>the</strong> inferior green developed by ferrous oxide,<br />

<strong><strong>an</strong>d</strong> <strong>the</strong> difficulties encountered in producing <strong>the</strong> colour, this<br />

subst<strong>an</strong>ce is seldom used for colouring enamels. The author<br />

has, however, found that a very h<strong><strong>an</strong>d</strong>some shade is obtained<br />

provided <strong>the</strong> ferrous oxide be used in a perfectly pure state,<br />

<strong>the</strong> depreciation of <strong>the</strong> colour being occasioned by <strong>the</strong> presence<br />

of o<strong>the</strong>r metals, more especially m<strong>an</strong>g<strong>an</strong>ese <strong><strong>an</strong>d</strong> copper, as well<br />

as by ferric oxide.<br />

Ferrous oxide c<strong>an</strong>not be used as such, because when pre-

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