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Enamels and enamelling; an introduction to the preparation and ...

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26 ENAMELS AND ENAMELLING.<br />

in<strong>to</strong> contact <strong>the</strong>rewith, <strong><strong>an</strong>d</strong> ch<strong>an</strong>ge in<strong>to</strong> soda crystals, which'<br />

dissolve in <strong>the</strong> water, calcined soda c<strong>an</strong> be used for purposes<br />

for which a solution of soda is required, <strong><strong>an</strong>d</strong> is often purchased,,<br />

in preference <strong>to</strong> <strong>the</strong> crystals, in order <strong>to</strong> save expense of dead<br />

freight on <strong>the</strong> water of crystallisation.<br />

For enamel m<strong>an</strong>ufacturers, of course, water is a useless<br />

encumbr<strong>an</strong>ce ; <strong><strong>an</strong>d</strong> <strong>the</strong>y, <strong>the</strong>refore, buy calcined soda exclusively.<br />

As, however, <strong>the</strong> ordinary calcined soda, even when<br />

perfectly white in appear<strong>an</strong>ce, always contains a notable proportion<br />

of iron compounds which spoil <strong>the</strong> colour of enamel<br />

by producing a yellow tinge, this soda c<strong>an</strong> only be used for<br />

enamels wherein colour is <strong>an</strong> unimport<strong>an</strong>t consideration.<br />

Enamel Soda.<br />

The trade in soda for enamel-making having developed<br />

considerably, alkali makers now comply with <strong>the</strong> dem<strong><strong>an</strong>d</strong> for<br />

a non-ferruginous soda <strong><strong>an</strong>d</strong> supply, under <strong>the</strong> name of " enamel<br />

soda," a product which may be regarded as perfectly free from<br />

iron. To this end <strong>the</strong> soda is purified by frequent crystal-<br />

lisations until <strong>the</strong> most delicate reagents fail <strong>to</strong> reveal <strong>the</strong><br />

presence of iron, except in traces, <strong>the</strong> product being afterwards<br />

spread out in heated rooms until thoroughly dry.<br />

Enamel soda is, it is true, dearer th<strong>an</strong> <strong>the</strong> ordinary kind ;<br />

but it furnishes a pure white enamel, whereas <strong>the</strong> ordinary<br />

soda, even when fairly pure, gives rise <strong>to</strong> a yellowish tinge,<br />

<strong>the</strong> extent of which depends on <strong>the</strong> amount of iron present.<br />

Kelp.<br />

This article of commerce is <strong>an</strong> impure soda obtained by<br />

calcining<br />

seaweed on <strong>the</strong> Irish <strong><strong>an</strong>d</strong> Scottish coasts. As it<br />

contains a number of o<strong>the</strong>r salts in addition <strong>to</strong> sodium car-<br />

bonate it is unsuitable for <strong>an</strong>y but <strong>the</strong> commoner kinds of<br />

enamel. Since <strong>the</strong> development of <strong>the</strong> m<strong>an</strong>ufacture of soda<br />

from common salt, <strong>the</strong> trade in this impure soda has greatly<br />

declined.

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