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Enamels and enamelling; an introduction to the preparation and ...

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30 ENAMELS AND ENAMELLING.<br />

large tubs, a residue is obtained, consisting for <strong>the</strong> most part<br />

of calcium carbonate <strong>to</strong>ge<strong>the</strong>r with a small amount of potash<br />

salts, <strong><strong>an</strong>d</strong> almost all <strong>the</strong> ferric oxide present in <strong>the</strong> wood ashes.<br />

In point of quality this product is comparable with ferrugin-<br />

ous limes<strong>to</strong>ne <strong><strong>an</strong>d</strong> is <strong>the</strong>refore of but very low value as a<br />

material for <strong>the</strong> <strong>preparation</strong> of enamel.<br />

This alkaline earth, which resembles lime but is more<br />

sparingly soluble, occurs in nature as magnesium carbonate<br />

(magnesite), <strong><strong>an</strong>d</strong> magnesium sulphate (Epsom salts); <strong><strong>an</strong>d</strong> as<br />

already stated,flkloniite consists of varying proportions of <strong>the</strong><br />

nates of lime <strong><strong>an</strong>d</strong> magnesia. Magnesium carbonate is<br />

net with as a m<strong>an</strong>ufactured product in commerce.<br />

Magnesium Carbonate.<br />

Small qu<strong>an</strong>tities of this salt are used in <strong>the</strong> m<strong>an</strong>ufacture<br />

of enamels, <strong>to</strong> reduce <strong>the</strong>ir fusibility ; <strong><strong>an</strong>d</strong> freedom from iron<br />

is a particularly import<strong>an</strong>t consideration. Good magnesium<br />

carbonate must form a pure white, very light mass, that c<strong>an</strong><br />

be easily reduced <strong>to</strong> <strong>an</strong> impalpable powder by rubbing between<br />

<strong>the</strong> fingers.<br />

Magnesium Sulphate (Epsom Salts).<br />

This subst<strong>an</strong>ce appears in <strong>the</strong> form of colourless, readily<br />

soluble crystals of very bitter taste, <strong><strong>an</strong>d</strong> parting with <strong>the</strong>ir<br />

water of crystallisation when *heated. It is not very often<br />

used in <strong>the</strong> <strong>preparation</strong> of enamels.<br />

LEAD COMPOUNDS.<br />

The silicates of lead being colourless <strong><strong>an</strong>d</strong> readily fusible,<br />

compounds of this metal are frequently employed for producing<br />

fusible enamels, <strong>the</strong> most common forms being <strong>the</strong><br />

oxides (litharge <strong><strong>an</strong>d</strong> red lead) or <strong>the</strong> carbonate (white lead).

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