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Enamels and enamelling; an introduction to the preparation and ...

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RAW MATERIALS FOR THE MANUFACTURE OF ENAMELS. 17<br />

Quartz s<strong><strong>an</strong>d</strong> resulting from <strong>the</strong> decomposition of gr<strong>an</strong>ite<br />

or gneiss, mostly contains small qu<strong>an</strong>tities of <strong>the</strong> minerals<br />

associated with quartz in <strong>the</strong>se rocks. These minerals,<br />

however, are felspar <strong><strong>an</strong>d</strong> mica, <strong>the</strong> former in <strong>the</strong> state of<br />

(generally white) crystals, whilst <strong>the</strong> latter is generally in <strong>the</strong><br />

condition of very tine crystalline flakes, green or black in<br />

colour. The presence of <strong>the</strong>se impurities in quartz s<strong><strong>an</strong>d</strong><br />

greatly reduces <strong>the</strong> value of <strong>the</strong> latter for our purpose ; since,<br />

on <strong>the</strong> one h<strong><strong>an</strong>d</strong>, <strong>the</strong>y considerably diminish <strong>the</strong> fusibility of<br />

<strong>the</strong> glass, <strong><strong>an</strong>d</strong>, on <strong>the</strong> o<strong>the</strong>r h<strong><strong>an</strong>d</strong>, mica [imparts a strong<br />

coloration <strong>to</strong> <strong>the</strong> product. As it is a difficult, <strong><strong>an</strong>d</strong> on a large<br />

scale impracticable, operation <strong>to</strong> purify <strong>the</strong> quartz s<strong><strong>an</strong>d</strong> from<br />

<strong>the</strong>se admixtures, such s<strong><strong>an</strong>d</strong>s must be discarded when <strong>the</strong><br />

production of fine glass is in question, though <strong>the</strong>y may be<br />

adv<strong>an</strong>tageously employed for making commoner qualities.<br />

In m<strong>an</strong>y places fine-grained s<strong><strong>an</strong>d</strong>s<strong>to</strong>nes are met with,<br />

consisting almost entirely of pure quartz s<strong><strong>an</strong>d</strong>, <strong>the</strong> individual<br />

grains of which are cemented <strong>to</strong>ge<strong>the</strong>r by a relatively small<br />

amount of lime. When treated in a suitable m<strong>an</strong>ner <strong>to</strong> get<br />

rid of this lime, s<strong><strong>an</strong>d</strong>s<strong>to</strong>nes of this class form a very useful<br />

source of silica for glass- or enamel-making.<br />

An excellent material for enamels <strong><strong>an</strong>d</strong> tine glass is afforded<br />

by <strong>the</strong> so-called infusorial or dia<strong>to</strong>maceous earth (Kieselguhr)<br />

which occurs as a fine, nearly pure white mass, so soft as <strong>to</strong><br />

be easily reduced <strong>to</strong> <strong>an</strong> almost impalpable powder by rubbing^<br />

between <strong>the</strong> fingers. Microscopic examination shows this<br />

wrongly named " infusorial earth " <strong>to</strong> consist of <strong>the</strong> siliceous<br />

integument of dia<strong>to</strong>ms, polythalamia <strong><strong>an</strong>d</strong> o<strong>the</strong>r lower or-<br />

g<strong>an</strong>isms, <strong>the</strong> org<strong>an</strong>ic constituents of which have entirely dis-<br />

appeared, leaving behind only <strong>the</strong> outer shells of nearly pure<br />

silica.<br />

For <strong>the</strong> purposes of <strong>the</strong> glass-maker, however, dia<strong>to</strong>maceous<br />

earth is a somewhat troublesome material <strong>to</strong> deal with in<br />

working on a large scale, being so bulky as <strong>to</strong> give rise <strong>to</strong><br />

2

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