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a study of the quality of a local herbal tea and volatiles of parinari ...

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alcohols, aldehydes, esters, e<strong>the</strong>rs, ketones, phenols, oxides <strong>and</strong> o<strong>the</strong>r specific<br />

compounds containing ei<strong>the</strong>r sulphur or nitrogen (Heath, 1978). While monoterpenes<br />

(C10) are <strong>the</strong> lower boiling point fraction <strong>of</strong> essential oils, sesquiterpenes (C15) are mainly<br />

found in <strong>the</strong> higher boiling point fraction. The diterpenes (C20) <strong>and</strong> triterpenes (C30) are<br />

generally eliminated by distillation (Cro<strong>tea</strong>u, 1980). While terpenes contribute negligibly<br />

to <strong>the</strong> flavour pr<strong>of</strong>ile, <strong>the</strong>y act as a carrier <strong>of</strong> less volatile constituents <strong>and</strong> thus<br />

influencing odour (Heath, 1978).<br />

2.4 Biogenesis <strong>of</strong> aroma compounds<br />

Many flavours, especially those in fruits <strong>and</strong> vegetables, are <strong>the</strong> secondary products <strong>of</strong><br />

various metabolic pathways (Fisher <strong>and</strong> Scott, 1997). There are three main classes <strong>of</strong><br />

compounds in relation to aroma biogeneration; <strong>the</strong>se are fatty acids, amino acids, <strong>and</strong><br />

carbohydrates (Sanz et al., 1997). Secondary metabolites act as an interface between <strong>the</strong><br />

producing organism <strong>and</strong> its environment, <strong>the</strong>y may be produced to combat infectious<br />

diseases, to attract pollinators <strong>and</strong> to discourage or encourage herbivores (Fisher <strong>and</strong><br />

Scott, 1997). Several pathways are involved in aroma biosyn<strong>the</strong>sis; <strong>the</strong>se have not been<br />

fully described but appear to be common for different fruits (Sanz et al., 1997).<br />

2.4.1 Metabolism <strong>of</strong> fatty acids<br />

Fatty acids seem to be <strong>the</strong> major precursors <strong>of</strong> volatile compounds responsible for aroma<br />

<strong>of</strong> most plant products (Sanz et al., 1997). The character impact compound for a<br />

particular flavour or aroma is a unique chemical substance that provides <strong>the</strong> principal<br />

sensory identity (McGorrin, 2002). Many character impact compounds responsible for<br />

<strong>the</strong> fresh, green, <strong>and</strong> fruity notes <strong>of</strong> fruits <strong>and</strong> vegetables are derived from fatty acids<br />

(Berger, 2007). Natural plant <strong>volatiles</strong>, such as aliphatic esters, alcohols, acids <strong>and</strong><br />

11

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