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a study of the quality of a local herbal tea and volatiles of parinari ...

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Esters constituted (83.3 % %) while alcohols s comprised (16.7 %) <strong>of</strong> <strong>the</strong> total number <strong>of</strong><br />

compounds identified in S. cocculoides upon using SPME. In contrast, using <strong>the</strong> CFMD<br />

method, resulted into ester esters (33.3%), alcohols (33.3 %) <strong>and</strong> carbonyls s (33.3 %) in ripe<br />

fruits. The unripe fruits provided only one alcohol when CFMD was used. used<br />

Figure 4.2 Structures <strong>of</strong> compounds extracted from <strong>the</strong> headspace <strong>of</strong> S. cocculoides<br />

fruit pulp using SPM SPME<br />

Using <strong>the</strong> he SPME method, isobutyl acetate, 22-methyl<br />

butyl acetate, , ethyl 2 methyl<br />

butyrate, 2.6 di-ter butyl-4-methyl-phenol,<br />

butyl-2-methyl butyrate, <strong>and</strong> geranyl acetate<br />

were identified (Figure 4.2 4.2). The CFMD method provided ethyl 2 methyl butyrate,<br />

2 butoxy ethanol <strong>and</strong> 1-oxiranylethanone.<br />

It is interesting that ethyl 2-methyl 2 butyrate<br />

was identified in S. cocculoides using both <strong>the</strong> SPME <strong>and</strong> <strong>the</strong> CFMD method. Due to its<br />

low odour threshold <strong>and</strong> fruity aroma aroma, ethyl 2-methyl methyl butyrate is considered consider to be one <strong>of</strong><br />

<strong>the</strong> important contributors to <strong>the</strong> characteristic sweet, apple apple-like like odour <strong>of</strong> California<br />

skullcap (Scullaria Scullaria californica A. Gray) flowers (Takeoka et al., ., 2008), <strong>and</strong> Rambutan<br />

fruit (Nephelium Nephelium lappaceum L.) aroma (Ong et al.,1998). The presence e <strong>of</strong> geranyl acetate<br />

in S. cocculoides using SPME has been hi<strong>the</strong>rto unreported unreported.<br />

65

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