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Figure 4.2.18 Weights <strong>of</strong>variables (compounds) in 3 tint PCs extracted by PCA utilizing sUe values or5 selected 4-, 5-ring PAH
-s: Cl 5 4 3 .a; ;0 2 .2: '" -.!l1 ::l 1 E ::l U 0 -1 -2 - - 66.4% 4-ring 5-ring c:::::::J Fa c:::::::J BbF/BkF c:::::::J Py c:::::::J BeP/BaP c:::::::J BAlChy 16.0% , PC1 PC2 Principal Components 10.5% '" b _ PC3
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POLYCYCLIC AROMATIC HYDROCARBONS IN
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composition. Portions ofthe lake th
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TABLE OF CONTENTS . ABSTRAcr._._ _
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6. CONCLUSIONS_._ _....._._._ _ ._
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FIGURE 3.104 CONfIGURATION OF ISOCH
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FIGURE 4 .2.12 SAMPLES AND PROMINEN
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fIGURE 5.3.1 DESCR1Pl1VE MODEL OF S
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APPENDIX B 3 _ T HEoerwt Of A PtUNC
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Ip » Ideno(l,2.3 cd)pyrene NIST =
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Figure L 1.1 The 16 parental polycy
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After release by the primary source
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decomposition processes (O'Malley e
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Figure 2.1.1 The Great Lakes draina
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;: Duluth Chicago 1 J Lake Superior
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are the Black River, the Cuyaho ga
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Figure 1.1.5 The pattern of permane
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sedimentary basins, Western. Centra
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Figure 2. 1.8 Summer (July) air and
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Natural Resources: The lower Great
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American waters under the current U
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continuously overflowed com bined s
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3.1 EXPERIMENTAL 3. METHODS 3.1.1 S
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Table 3,1.1 Locations and types ofs
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Figure 3.12 Extraction and purifica
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hexane. 2) the unsaturated aliphati
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this problem. Ratios ofthe two stab
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Figure 3. 1.4 Configuration ofIsoch
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3.2.1 UNl- AND BIVAJUATE METHODS Th
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f igure 3.2. 1 Mean and range (± s
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utilized the same instrument (Isoch
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Selecting lIt1J'iahlu: It was demon
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w- _ 71
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seven variables with fewer missing
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analysis also employed a greate r n
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description. The second cluster ana
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elationships between different site
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Figure 4.1.3 Regression ofthree fir
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Figure 4.[.5 Isotopic composition (
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Figure 4.1.6 Weights ofvariables (c
Page 120: Figure 4.1.8 Distri bution ofsample
Page 123 and 124: those at the majority ofstations. S
Page 126 and 127: Ion, 969, 971, 357, 358). In additi
Page 129: Figure 4.2.3 Samples and prominent
Page 132 and 133: analysis supported some ofthc previ
Page 135 and 136: , ", Is , , >\ ryr " II ,- - , I ,
Page 137 and 138: 11'
Page 139: sources (Fi g. 4.2 .5c). This compo
Page 143: Figure 4.2.7 The relative contribut
Page 146 and 147: ".1.1.2 Miring CllrIIU (isotopic co
Page 149: Figure 42.9 Samples and promin ent
Page 157: Figure 4.2. 13 Samples and prominen
Page 168 and 169: It is difficult to differentiate be
Page 172: Figure 42.19 Distribution ofsamples
Page 175 and 176: 5.1 SPATIAL DI STRIBUTION s. DISCUS
Page 177: f igure 5.1.1 Zones coinciding with
Page 180: f igure 5. 1.2 Average and range (
Page 184: Figure 5.1.4 Zones (clusters) in th
Page 187: Figure 5.1.5 Direction ofthe mean s
Page 191 and 192: The location ofthe third station at
Page 193: Figure 5.1.7 Station locations and
Page 197: Figure 5.1.8 Station locations and
Page 201 and 202: 5.1.4 and Section 4.1.2). This clus
Page 204: Figure 5.1.1 1 Statioo locations an
Page 208 and 209: unaffected by the contaminated flow
Page 211 and 212: this station is die clo$esf to the
Page 213 and 214: samples and sources (Fig. 52.1 and
Page 216 and 217: There is yet another observation po
Page 218 and 219: with the relative contribution ofdi
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Table S.l.1 Six dusters identified
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the three previous ly identified zo
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Figure 5.2.4 Station locations and
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contribution from petroleum related
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(Fig. 4.2.7). Finally. this site co
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Snow melt and sewer releases seem t
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importance ofcombustion-derived PAR
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Intens ity o(degradation (the South
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where this importance is somewhat r
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Figure 5.2.5 Station tocatices andz
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:2 for molecular composition assume
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ange of Slatistica1 variat ion of t
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Figure 5.].1 Descriptive model ofso
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conveyed into the river through dir
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molecular composition. Its applicat
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Canton L. and Grimal t 1. O. (1992)
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Howell E. T., Marvin C. H., Bilyea
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Olson F. C. W. (l950) The currents
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Willett P. (1981) Similarity and cl
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t Apprndb AI. [cout.) bl S,.lioD A<
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Appendill A6. The two-component mas
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Appendix A7. (cont.) Xl. = X llVt r
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• ass
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Appendix 82. (cont.)
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Appendix IU. (cant.) oj Tue Dec 24
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AppendiI C3. (cont.) Coo c.eo lrati
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