COST 507 - Repositório Aberto da Universidade do Porto

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75Nar Narita K., Trans. ISI, 15 (1975) 145-151 76Ero Eron'yan M.A., Avarbe R.G., Danisina T.N., High Temperature 14 (1976) 359-360 78Mas Maslov V.M., Neganov A.V., Borovinskaya I.P., Merzhanov A.G., Fiz.Goreniya Vzryva, 14(6) (1978) 73-82 78Mat Matsuda S., Okumura N., Trans. ISIJ, 18 (1978) 77 82Kun Kunze J., Metal Science, 16 (1982) 217-218 84Etc Etchessahar E., Bars J.P., Debuigne J., Less Comm.Metals, 134 (1984) 123-139 85JAN JANAF Thermochemical Tables, 3 rd ed.J.Phys.Chem.Ref.Data 14 (1985) Suplement No.l 850th Ohtani H., Tanaka T., Hasebe M., Nishizawa T., Solubility of NaCl- Type Carbides (NbC, VC and TiC) in Austenite. Japan-Canada seminar on Secondary Steelmaking, Dec.3-4 (Tokyo, Japan) (1985) J-7 -12 85Wad Wada H. and Pehlke R.D., Metall Trans.B, 16B (1985) 815-822 85Wol Wolff L., Bastin G., Heijligers H., Soid State Ionics, 16 (1985) 105-112 87Wri Wriedt H.A., Murray J.L., Bull.Alloy Phase Diagrams, 8 (1987) 378-388 88DeB De Boer F.R, Boom R., Mattens W.C.M., Miedema, Niessen A.K., Cohesion in Metals, Cohesion and Structure, vol.1 I s ' ed., (1988) 88Len Lengauer W., Ettmayer P., Mater. Sci.Eng. A, 105/106 (1988) 257-263 89Ber Berkane R., thesis, Universite de Nancy I (1989) 89Tur Turkdogan E.T., Trans Iron Steel Inst. (1989) 61-75 90Oht Ohtani H. and Hillert M. CALPHAD 14 (1990) 289-306 90Ozt Ozturk B., Frerehan R.J., Metall.Trans., 21 Β (1990) 879-884 90Via Viala J.C., Vincent C, Vincent H., Bouix J., Thermodynamic Approach to the Interaction Chemistry Between Aluminium and Titanium Carbide, Mater.Res.Bull.,25 (1990) 457-464 91Din Dinsdale A. CALPHAD 15 ( 1991 ) 317-425 91Fri Frisk K., CALPHAD, 15 ( 1991 ) 79-106 91Len Lengauer W., Acta Metall.Mater.39 (1991) 2985-2996 91Lih 92BaI 92Cla 92Ko Lihrmann J.M., Herve P., Petitet J.P., 2 nd European Ceramic Society Conference, Augsburg (Germany) (1991) Balasubramanian K., Kroupta Α., Kirkaldy S.J., Met.Trans A, vol.23 A (1992)709-727 Clark E.B. and Roebuck B., Extending the Application Areas for Titanium Carbonitride Cermets, Refractory Metals & Hard Materials 11(1992)23-33 Kornilov A.N., Chevlovskaya N.V., Shveikin G.P., Khim.Fak.,Mosk. Gos. Univ.,Moscow, Deposited Doc, VINITI (1982) 987-992 92Lee Lee B.J., CALPHAD, 16(2) (1992) 121-149 92 Zou Zou Η. and Kirkaldy J.S., Thermodynamic Calculation and Experimental Verification of the Carbonitride-Austenite Equilibrium in Ti-Nb Microalloyed Steels, Metall.Trans. A, 23A (1992) 2, 651-657 93Jon 94Sau 95Alb Jonsson S., Ph. D.Thesis; Phase Relations in Quaternary Hard Materials, KTH Stockholm, 1993 Saunders N., COST 507, Concerted Action on Materials Sciences, Thermochemical Database for Light Metal Alloys, I.Ansara ed., ECSC-EEC-EAEC, Brussels, (1994) 52 Albertsen K. and Schaller Η-J. Constitution and Thermodynamic of the - 184 -
Ti-C, Z.Metallkd. 86 (1995) 5 319325 95Grö Gröbner J., Lukas HL., Aldinger F., Thermodynamic calculations in the Y- Al-C system, J.Alloys and Comp. 227 (1995) 9396 95Fri Friec Y.L., Bauer J., Rogl P., unpublished work, University of Vienna (1995) 95Mes Meschel S.V., Kleppa O.J., Standard enthalpies of formation ofAlB I2 and AI4C3 by high temperature direct synthesis calorimetry, J.Alloys and Comp. 227(1995)9396 95Sau Saunders N., NiTi, unpublished work 96BeI Bellen P., Hari Kumar K.C., Wollants P., Z.Metallkde, 87(12) (1996) 97278 96aJon Jonsson S., Assessment of the Ti-N System, Z.Metallkd. 87 (1996) 9, 691702 96bJon Jonsson S., Assessment of the Ti-C System, Z.Metallkd. 87 (1996) 9, 703712 96cJon Jonsson S., Calculation of the Ti-C-N System, Z.Metallkd. 87 (1996) 9 713720 96dJon Jonsson S., Assessment of the Ti-W-C System and Calculations in the Ti-W-C-N System, Z.Metallkd. 87 (1996) 10, 788795 96Luk Lukas HL., unpublished work for AlC modified using Meschel 's calorimetrie enthalpy of ALjC 3 96Sei Seifert ΗJ., Lukas H.L., Petzow G., Thermodynamic Optimization of the Ti-C System, J. of Phase Equilibria, 17 (1996) 1, 2435 96Zha Zhang F. and Chang Y.A., private comunication (1996) 96Zen Zeng K. and SchmidFetzer R., Critical Assessment and Thermodynamic Modeling of the Ti-N System, Z.Metallkd. 87(1996)7 540554 97Che Chen Q., Thermodynamic Assessment of The Ti-Al-N System, unpublish work, (1997) 97Dum Dumitrescu L.F.S., Sundman Β., A Thermodynamic reassessment of the Ti-C and Ti-C-N systems, unpublished work, (1997) 97Jon Jonsson S. Assessment of the Fe-Ti-C System, Calculation of the Fe-Ti-N System and Prediction of the Solubility Limit ofTi(C.N) in liquid Fe, unpublished work , (1997) 97Sau Saunders N., Reassessment of the Fe-Ti, unpublished work, 1997 97Sch Schuster J.C., Du Y., unpublished work (1997) 97Zen Zeng Κ. and Schuster J.C., Thermodynamic Modeling and Applications of the Ti-Al-N Phase Diagram, presented at Orlando, Florida, Feb. 1997 185
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European Commission COST European c
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European Commission COST European c
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Preface The Final Workshop of the C
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COST 507 STRUCTURE Measurement and
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GRl: Mirtee S.A., Volos Mr.P.Polati
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D9 Dll Fl GR2 II NI S3 SF1 "Thermop
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A Summary of the COST 507 Action an
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Aluminium-based systems Titanium-ba
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An Example using the COST 507 Datab
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Appendix COST 507: Some Key Meeting
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Al - 0.5 Fe, 1 Mg, 0.8 Mn, 0.2 Si (
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Fig 4 Aluminium beverage cans. The
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Fig 6 High pressure compressor vane
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INTRODUCTION All of us are aware of
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In the interaction with materials a
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There was a first warning more than
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Some time ago, the well-known physi
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Today there is a whole range of ins
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The dimension of this reservoir inc
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REFERENCES [ 1 ] G. Petzow, "Man, M
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Trends in Application of Materials
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Raw Materials The Cycle of Material
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i LÌ i.'»Af·· iù^ VV.V.X. iTTa
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1600 OJ 1200 .« 1100 d 1000 900 Si
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Al Phase Relations in the Aluminium
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oundaries of the single phase regio
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Table 1 : Crystallographic Data of
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order to facilitate the evaluation
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(especially around 33 at% Mg) in or
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3.System Ti-Sn-Al-N. The investigat
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6) N.Durlu, U.Gruber, M.Pietzka, H.
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Summary of final report Directional
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calculate the thermodynamic mixing
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Introduction It is the aim of this
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Thermodynamic evaluations for high
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Figure 5 presents the calculated li
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There is a complete lack in the lit
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a.B5 ø.ia 0.15 0.20 0.25 0.30 0.35
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700 [53Phi] 800 +[90Kuz21 ]iquld a
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Thermodynamic Assessments, Experime
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AIN and TiNi_ x is also given. Vari
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satisfied the three requirements of
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84Bey R. Beyers, R. Sinclair, and M
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Material and Methods 2.1 Fabricatio
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3.4 Electronmicroscopy (SEM) and X-
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Tab. 3: Density of the Ti20Albase
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Tab.5. continued TÌ20A1 5CulONi Ti
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Fig. 3: ESMA and Xray diffraction
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Fig.7: Wetting angle of Ti 15A1 lOC
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Thermophysical Properties of Light
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Tab.2 Chemical composition of terna
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700 (AI)+AIFeS¡«_600 KS1275.1 l
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4.2 Thermal conductivity of industr
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4.3 AlSiZn alloys Electrical re
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94Jar/Bra G.Jaroma-Weiland, R.Brand
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MgZn9 (C 14) and Mg2Zn u in the Al
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The three Laves phases were describ
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References [13Ege] G. Eger, Z. Meta
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0.30 0.35 0.40 0.45 0.50 mole fract
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□ [48Koe] 600 500 400 0 0.1 0
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MggZn,, this work □ Single phase,
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Temperatures in °C 0.05 0.10 mole
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Table 2 : Alloy compositions Alloy
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All. Dy 50 Cpexp °C Cpadd Table 5
Page 137 and 138: Zn ¿Kl Si Fig. 2 : Position of the
Page 139 and 140: 22.5 ■■ 7.5 Temperature ICI Tem
Page 141 and 142: .to 2.5 "lõõ soo iÍOõ dOõ rtõ
Page 143 and 144: GR2 Differential Scanning Calorimet
Page 145 and 146: Time (x10 3 sec) Fig. 1. DSC Thermo
Page 147 and 148: solidification. It can be seen that
Page 149 and 150: 4. Conclusions Differential scannin
Page 151 and 152: COST 507 - ROUND Π UNIT II SEZIONE
Page 153 and 154: [96Sac] The Rrich regions of the
Page 155 and 156: List of publications in the framewo
Page 157 and 158: 2Contributions: oral or posters p
Page 159 and 160: 1996 REPORT 2 s ' PART: ACTIVITY CA
Page 161 and 162: [96Sei] Excess Gibbs energy coeffic
Page 163 and 164: List of publications in the framewo
Page 165 and 166: Proc. :7 th Meeting on "Syntheses a
Page 167 and 168: 2.1 Solid solubility measurements T
Page 169 and 170: eviews by Rivlin and Raynor [81 Riv
Page 171 and 172: inaires. Thesis, Universite Scienti
Page 173 and 174: Table 1. Review of the ternary phas
Page 175 and 176: L) Liq+bcc=FeSi+t_1 M) Liq+t 1=FeSi
Page 177 and 178: Extrapolations based on Ti-C-N S3 B
Page 179 and 180: value has been accepted in all thre
Page 181 and 182: with high precision whereas Jonsson
Page 183 and 184: only fit the hightemperature asym
Page 185 and 186: Jonsson combined his descriptions o
Page 187: Table II. Solubility product of TiC
Page 191 and 192: 1000 1500 2000 2500 3000 Τ (K) Fig
Page 193 and 194: o Oí o 3 4 5 6 7
Page 195 and 196: M^øD^ O Kelley(1944) • Kelley an
Page 197 and 198: — cale, with Dumitrescu (1997) -
Page 199 and 200: € gfc-π m-, .-π-, π-π .-saa J
Page 201 and 202: +graph 0 TiN 0.2 0.4 0.6 X TiC 0.8
Page 203 and 204: Binder et al (1992) TiN 1423 K ■
Page 205 and 206: 0.08 600°C 700°C 800°C 900°C 10
Page 207 and 208: [59Sto]: Ä600°C □ 70D°C O8Q0°
Page 209 and 210: 2000 Cale, with Saunders (1997) —
Page 211 and 212: An Experimental Investigation of th
Page 213 and 214: An Experimental Investigation of th
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Page 217 and 218: EXPERIMENTAL INVESTIGATION OF THE C
Page 219 and 220: Fig.1 SEM micrographs of CuMgZr
Page 221 and 222: ■ 888 24 HSM^«" 16—19 3 À I
Page 223 and 224: Thermodynamic Evaluations of the Al
Page 225 and 226: Fcc_Al aves_C15 ONU ΔΝ12 αΝ13
Page 227 and 228: 2.2 Assessment The optimisation of
Page 229 and 230: 0.50 0.45 CulOZr7/ 0. 40 Or ^ 0.3
Page 231 and 232: References [71Kri] Kripyakevich, P.
Page 233 and 234: Kejun Zeng and Marko Hämäläinen,
Page 235 and 236: for detennining phase boundary and
Page 237 and 238: Table 2 Al-Fe-Mn results wt%Fe 0.5
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•00 Γ Ι I I I ~ LIQUID S^ 7iO
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the observed A2-B2 ordering. This p
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1473K Ahmed & Flower [94 Ahmi] 0.2
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900K Paruchuri & Massalski [91Par]
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BCC_B2#2 TI3RL TIPL BCC B2#2 TIRL
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0.2 0.3 0.4 0.5 X(LIQ,V) Figure 15
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1 Introduction and Overview of the
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at least 95% by Fe, possibly 99%, a
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8 References 43Phi H W L Phillips,
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1050 1000 Isopleth, Al - Si - 4 wt
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Al-Mn-Si 873 K 0.90 Liquid 0.80 0.7
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A Thermochemical Assessment of Data
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certainly due to the appearance of
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Materials Science Centre, November
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1400 Al-Mn Fig 2 Calculated partial
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1000 ι AlMn I Ι 950 Liquid E ω
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Al-Fe-Mn 843 K 0.90 0.80 0.70 0.60
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AlFeMn section at 2 wt% Mn co
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0.50 0.45 0.40-1 LU £ 0.35 LU 0.30
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European Commission EUR 18171 —CO
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NOTICE TO THE READER Information on
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