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(BRAVO) Study: Final Report. - Desert Research Institute

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<strong>Final</strong> <strong>Report</strong> — September 2004<br />

presentation of merged data is the assumption that the good correspondence in Texas for the<br />

two years also applies to Mexico.)<br />

Sept. & Oct. 1996 & 1999 S<br />

1155<br />

1126<br />

867 998 1272<br />

651 605<br />

1102<br />

1048<br />

610<br />

835<br />

1133<br />

651 1078 1215<br />

875<br />

893<br />

981 1187<br />

1391<br />

1050<br />

989<br />

776 792 943 1199 1200<br />

1386<br />

1109<br />

870 879 1101<br />

1087<br />

903 1048<br />

990 1147 1443<br />

1271<br />

1154 1281<br />

1308 1133<br />

1350<br />

690 750<br />

1350<br />

900<br />

1350<br />

1050<br />

1433 1086<br />

1124<br />

1050 1200<br />

1200 1350 1500 1586<br />

1996 & 1999 means for collocated sites<br />

1224<br />

Site<br />

1996<br />

Big Bend<br />

870<br />

Amistad<br />

1386<br />

Fort Lancaster 1215<br />

Lake Corpus Christi 1281<br />

Everton Ranch 1109<br />

OjinagaPresidio 776<br />

Guadalupe Mts. 605<br />

1999<br />

879<br />

1101<br />

1078<br />

1154<br />

1087<br />

792<br />

651<br />

Figure 10-6. Composite of mean sulfur concentrations (ng/m 3 ) measured during September<br />

and October in 1996 (the preliminary study) and 1999 (the <strong>BRAVO</strong> <strong>Study</strong>).<br />

Figure 10-6 shows that mean fine sulfur concentrations across Texas and Mexico in<br />

September and October were greatest in eastern Texas, near the Carbón plants and around<br />

the Monterrey area (at the southern end of the contours). In general, particulate sulfur<br />

concentrations decreased from east to west.<br />

Returning to the 1999 <strong>BRAVO</strong> measurements alone, the highest fine particulate<br />

sulfur concentrations at Big Bend during the <strong>BRAVO</strong> study period occurred during four<br />

episodes – August 21, September 1-2, September 14-15, and October 12. The Sept. 1-2<br />

episode also had the highest organic carbon and second highest elemental carbon<br />

concentrations of the <strong>BRAVO</strong> study. The spatial concentration patterns for these four<br />

episodes are all different, with the patterns for August 21 and October 12 being the most<br />

similar. The latter two days had higher sulfur concentrations in northeast Texas and around<br />

the Big Bend area while central Texas had lower values. September 15 had the highest sulfur<br />

concentrations around Big Bend and on the southern Gulf Coast while concentrations in<br />

northeast Texas were the lowest in the state. On September 1, the highest sulfur<br />

concentrations were in central Texas with the lowest being in three pockets on the east, far<br />

west, and southwest.<br />

10-9

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