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FIRE DESIGN OF STEEL MEMBERS - Civil and Natural Resources ...

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experienced in fire situations, but generally the thermal properties of the steel are<br />

assumed to stay constant for simplicity in calculations. The specific heat, density <strong>and</strong><br />

thermal conductivity do however vary with temperature, <strong>and</strong> although the difference<br />

does not usually effect the temperature of the steel found from analyses significantly,<br />

the differences should still be noted.<br />

Specific Heat:<br />

Of the thermal properties of steel, the specific heat has the largest deviation from a<br />

constant value. Stirl<strong>and</strong> (Purkiss, 1996) suggested that the specific heat of steel, c s , be<br />

taken as:<br />

c<br />

s<br />

2<br />

s<br />

−4<br />

−2<br />

= 475 + 6.010x10<br />

T + 9.46x10<br />

T<br />

1.3<br />

s<br />

This equation is valid for temperatures of the steel, T s, , up to around 750 °C when the<br />

specific heat of steel reaches a discontinuity which occurs due to a phase change at the<br />

molecular level of steel at this temperature.<br />

For the analyses performed here, <strong>and</strong> in most fire situations, this temperature is too low<br />

as the upper limit, so the equations used in this report are found in ENV 1993-1-2, as<br />

follows:<br />

c<br />

s<br />

−3<br />

2<br />

−6<br />

3<br />

425 + 0.773T<br />

s<br />

+ 1.69x10<br />

Ts<br />

+ 2.22x10<br />

Ts<br />

= 20 < T s < 600 °C 1.4a<br />

c 13002<br />

s<br />

= 666 −<br />

600 < T<br />

( T − 739)<br />

s < 735 °C 1.4b<br />

s<br />

c 17820<br />

s<br />

= 545 +<br />

735 < T<br />

( T − 731)<br />

s < 900 °C 1.4c<br />

s<br />

c = 650<br />

900 < T s < 1200 °C 1.4d<br />

s<br />

There are other formulas that are valid up to the discontinuity at around 750 °C, <strong>and</strong><br />

these are listed in various publications. V<strong>and</strong>amme <strong>and</strong> Janss derived the following<br />

relationship (Proe et al 1986):<br />

2<br />

s<br />

−4<br />

c = 3.8x10<br />

T + 0.2T<br />

+ 472<br />

1.5<br />

s<br />

s<br />

A graph of the specific heat using these equations is shown below in Figure 1.1:<br />

12

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