Standard X-ray Diffraction Powder Patterns

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$Standard X-ray Diffraction Powder Patterns$

$Standard X-ray Diffraction$

Powder data cardsCardnumber8-2110-54Indexlines3. 222. 372. 192. 033.203.25Bismuth Telluride (tellurobismuthite), BtTe3 (trigonal)Thompson [1].SourceVasenin and Konovalov [2].Additional published patterns. Harcourt [3]1942.NBS sample. The sample of bismuth telluridewas obtained as a single crystal from SemitronicsInc., Winchester, Mass. Spectrographic analysisshowed the following impurities: 0.0001 to 0.001percent each of magnesium and silicon.«The sample was a gray opaque powder.The d-values of the three strongest lines are:3.222, 2.376, and 2.192 LStructural data. Lange [4] in 1939 determinedthat bismuth telluride has the tetradymite structure with the space group DSd-R3m (No. 166) and3(Bi2Te3) per unit hexagonal celL19401940195119541963Lattice constantsFrondel [5]_ _-_-_-_-Peacock and Berry [6]__Donges [7]_ _ __Semiletov [8]__ .-.National Bureau ofStandards at 25 C__aA4. 394. 3844. 354.394. 3852cA^n 730. 4530. 330.4630. 48316hkl (hex.)0030061011040150181-0-100-1-111101130-0-151161-0-130-1-142051-0-160-0-180-2-102-0-111*1-150-2-130-0-210-1-201250-2-161-1-182-1-103000-1-232-1-131-1-212-0-201-0-252-1-160-1-26Internal Standard,Tungsten, a = 3. 1648 ACu, 1.5405 A at 25 CdA10. 165. 0783. 7673. 3983. 2222, 6892. 3762. 2382. 1922. 1422.0312. 1131. 9951. 8901. 812L 7021. 6931. 6111. 5651, 49011. 47561. 45131. 41401. 39701. 34491. 34041. 2986L 26601. 25141. 22421. 21031. 18861. 16101. 14641. 1201I373
Bismuth Telluride (tellurobismuthite), Bi2Te3 (trigonal)—ContinuedReferences [5][1] R. M. Thompson, The telluride minerals and their [6]occurrence in Canada, Am. Mineralogist 34, 342-382 (1949).[2] F. I. Vasenin and P. F. Konovalov, lonization x-ray [7] Estructure investigation of bismuth telluride, J. Tech.Phys. 26, part 7, 1376 (1956).[3] G. A. Harcourt, Tables for the identification of oreminerals by x-ray powder diffraction, Am. Mineralogist 27, 100 (1942). [8][4] P. W. Lange, Ein vergleich zwischen Bi2Te3 undBi2Te2S, Naturwissenschaften 27, 133 (1939).C. Frondel, Redefinition of tellurobismuthite andvandiestite, Am. J. Sci. 238, 880-888 (1940).M. A. Peacock and L. G. Berry, Rontgenographicobservations on ore minerals, Univ. TorontoStudies Geol. Ser. 44-48, 67 (1940-1943).Donges, Ober Chalkogenohalogenide dreiwertigenAntimons und Wismuts III. tlber Tellurohalogenidedes dreiwertigen Antimons und Wismuts undiiber Antimon und Wismut III-Tellurid und WismutIII-Selenid, Z. anorg. allgem. Chem. 265, 56 (1951).S. A. Semiletov, An electron diffraction study of filmsof Bi-Se and Bi-Te prepared by evaporation, TrudyInst. Krist. Akad. Nauk SSSR 10, 76-83 (1954).Bismuth Trioxide (bismite), alpha Bi2O 3 (pseudo-orthorhombic)Powder data cards.Cardnumbers6-02946-0307Indexlines3.261. 961. 753,232. 681.67Sille*n [1] 1941.SourceFrondel [2] 1943.NBS sample. The sample of bismuth trioxidewas obtained from Johnson, Matthey, and Co.,Ltd. Their spectrographic analysis showed thefollowing major impurities: less than 0.001 percent each of silicon aluminum, lead, silver, andsodium.The color of the sample was light yellow. Therefractive indices were top high to be determinedby the usual liquid-grain immersion method.The d-values of the three strongest lines are:3.253, 2.693, and 2.708 LStructural data. Sillfo [1] in 1941 determinedthat alpha bismuth oxide is monoclinic or pseudoorthorhombichaving the monoclinic space groupCV-P2!/c (No. 14), with 4(Bi2O3) per unit monocliniccell, or 8(Bi2O3) per unit pseudo-orthorhombiccell. According to Sill6n [1], themonoclinic indices hkl are transformed into thepseudo-orthorhombic indices h'k'l' by the following relationsThe lattice constants reported by Sill6n havebeen converted from kX to angstrom units forcomparison with the NBS values.hkl120111200031220040131211140102231022240122320051311151222331142340251400260302242, 420013322411113071351171062033431162360133Internal Standard, oTungsten, a = 3. 1648 ACu, 1.5405 A at 25 CdA5. 2764. 4984. 0843. 6223. 5173. 4563. 3103. 2533. 1842. 7532. 7082. 6932. 6382. 5592.5322. 4992.4292. 3902. 2442. 1762. 1542. 1382. 1322. 0412. 00641. 99221. 95841. 93171. 91361. 90981. 87871. 87201. 84091. 82371. 80871. 79671. 77901. 76601. 75901. 7549/2448219331002563839615976146652825426
Page 1 and 2: c ^r.
Page 3 and 4: UNITED STATES DEPARTMENT OF COMMERC
Page 5 and 6: Introduction.. _ __________________
Page 7 and 8: STANDARD X-RAY DIFFRACTION POWDER P
Page 9 and 10: D. E. Appleman, and D. Handworker.
Page 11 and 12: Ammonium Fluoberyllate, (NH4) 2BeF4
Page 13 and 14: Ammonium Fluoborate, NH4BF4 (orthor
Page 15 and 16: Arsenic Trioxide, claudetite, As2O3
Page 17 and 18: Powder data cardsBarium Stannate, B
Page 19 and 20: Bismuth Orthophosphate, BiPO4 (trig
Page 21: Bismuth Orthovanadate (high form),
Page 25 and 26: Cadmium Perchlorate Hexahydrate, Cd
Page 27 and 28: Cadmium Telluride, CdTe (cubic)Powd
Page 29 and 30: Calcium Fluoride Phosphate (fluorap
Page 31 and 32: Cesium Chromate, Cs>CrO 4 (orthorho
Page 33 and 34: Cobalt Fluosilkate Hexahydrate, CoS
Page 35 and 36: Copper Sulfate (chalcocyanite), CuS
Page 37 and 38: Erbium Arsenate, ErAsO4 (tetragonal
Page 39 and 40: Gallium Arsenide, GaAs (cubic)Powde
Page 41 and 42: Indium Arsenide, InAs (cubic)Powder
Page 43 and 44: Lanthanum Niobium Titanium Oxide, L
Page 45 and 46: Lithium Phosphate, high form, Li3PO
Page 47 and 48: Magnesium Ammonium Phosphate Hexahy
Page 49 and 50: Potossium Chlorate, KCIO3 (monoclin
Page 51 and 52: Potassium Zinc Decavanadate 16 Hydr
Page 53 and 54: Silver Antimony Telluride, AgSbTe2
Page 55 and 56: Sodium Trimetaphosphate, Na3P3O9 (o
Page 57 and 58: Sodium Trimetaphosphate Monohydrate
Page 59 and 60: Strontium 1:1 Berate, SrO-B2O3 (ort
Page 61 and 62: Thallium Chromate, Tl2CrO4 (orthorh
Page 63 and 64: Titanium Dioxide, brookite, TiO2 (o
Page 65 and 66: CUMULATIVE INDEX TO CIRCULAR 539, V

Standard X-ray Diffraction Powder Patterns

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