Standard X-ray Diffraction Powder Patterns

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$Standard X-ray Diffraction Powder Patterns$

$Standard X-ray Diffraction$

Potassium Chlorate, KC1O3 (monoclinic)Powder Data cardsCardnumber1-059912-571Indexlines3.452. 792.863.462.882.80SourceHanawalt, Rinn and Frevel[1] 1938.Institute of Physics, University College, Cardiff.Additional published patterns. None.NBS sample. The sample of potassium chloratewas obtained from the General Chemical Co.,New York, N.Y., and recrystallized to sharpenthe pattern. Spectrographic analysis showed thefollowing impurities: 0.001 to 0.01 percent eachof aluminum, barium, iron, rubidium, silicon,sodium, and strontium.The color of the sample was white. It isoptically negative with the indices of refractionNa =1.408, N0=L516, and N 7 = 1.524; 2V wasvery small.The d-values of the three strongest lines are:3.45, 3.34, and 2.868 A.Structural data. Zachariasen [2] and [3] in 1928determined that potassium chlorate has the spacegroup CS h P2i/m (No. 11) and 2[KC1031 perunit cell. The unit cell measurements of levingand Ozols and Zachariasen have been convertedfrom kX to angstrom units for comparison withthe NBS values.The density of potassium chlorate calculatedfrom the NBS lattice constants is 2.339 g/cm 3at 26 °C.References[1] J. D. Hanawalt, H. W. Rinn, and L. K. Frevel,Chemical analysis by X-ray diffraction, Ind, Eng.Chem. Anal. Ed. 10, 457-513 (1938).[2] W. H. Zachariasen, The crystal structure of sesquioxidesand compounds of the type ABOs, SkrifterNorske Videnskaps-Akad. Oslo I: Mat.-Naturv. Kl.Nr. 4, 82 (1928).[3] W. H. Zachariasen, The crystal structure of potassiumchlorate, Z. Krist. 71, 501 (1929).[4] A. levinS and J. Ozols, Precision determination oflattice constants of monoclinic crystals, DokladyAkad. Nauk SSSR »1, 527-30 (1953).hkl001T01Oil110002T02101012020111021120501102511, T13022112T22013203201213211221, 123122T04103023130113032T32131014223221214302T24123511303033513310040203005, 533215213323042Internal Standard,Tungsten, a==3.1648 ACu, 1.5405 A at 26 °CdA6. 694.414.293.453.343.2343.2042. 8682. 7942.7792.5792. 3562.3272. 3092. 1492. 1452. 1352. 1152. 0701.9191.9021.8151. 8001. 78881. 78001. 77301. 76151. 74211. 71491. 68001.62791. 61451. 61111. 60141. 58201. 57221. 55391. 54281. 49731. 48971. 48481. 47001. 42961. 42131. 41371. 39781. 35171. 33711. 32541. 31361. 30091. 289973105100603435332343182677172552121
Potossium Chlorate, KCIO3 (monoclinic)—ContinuedLattice constants192919531963Zachariasen [3]__-_ _______levies and Ozols [4]_ _ _National Bureau of Standards at26 °Ca0A4. 6564. 65694. 6553±.00026A5. 5965. 590895. 5905±.0006cA7.0997. 09917. 1006±.0005ft109°38 /109°38.9'109°41.1'±.3'Potassium Lithium Sulfate, KLiSO4 (hexagonal)Powder data cards. None.Additional published patterns. None.NBS sample. The sample of potassium lithiumsulfate was prepared at NBS by dissolving stoichiometricamounts of solid potassium hydroxide andlithium hydroxide in a small amount of water.When the mixture was at room temperature adrop of 1 percent bromcresol-purple was addedand the mixture neutralized with H2SO4 . Thesolution was evaporated to dryness and the precipitate was then heated to about 750 °C tosharpen the pattern. Spectrographic analysisshowed the following impurities: 0.01 to 0.1 percent each of calcium, indium, and sodium; and0.001 to 0.01 percent each of aluminum, rubidium,and silicon.The sample is colorless and optically negative.The indices of refraction are N0 = 1.471 and N e= 1.469.The d-values of the three strongest lines are:3.960, 3.099, and 2.573 A.Structural data. Nowacki [1] in 1942 determined that potassium lithium sulfate has thespace group CJ-P6/3 (No. 173) and 2(KLiSO4)per unit cell. The lattice constants of Nowackihave been converted from kX to angstrom unitsfor comparison with the NBS values.19421963Lattice constantsNowacki [1]. _______ _National Bureau ofStandards at 26°C__aA5. 145. 1457cAa 628. 6298hkl002101102110111103200112201, 004202113203210114,211105212204300213106205214220116222311,304206215107, 312313401, 224216402108403306Internal Standard,Tungsten, a = 3. 1648 ACu, 1.5405 A at 26 Cd0A4. 3203. 9603.0992. 5732.4652. 4182. 2252.2112. 1581. 9811. 9191. 7621. 6831.6531. 60961. 56901. 54991. 48521. 45331. 36871. 36471, 32761. 28641. 25501. 23291. 22371. 20811. 20551. 18801. 13561. 10481. 09391. 07871. 04841. 03891. 03357121007034165820191242311511411223355262331212111The density of potassium lithium sulfate calculated from NBS lattice constants is 2.385g/cm3 at at 26 °C.Reference[1] W. Nowacki, Beziehungen zwischen K[AlSiO 4 ] (Tiet-Kaliophilit), Ba[Al2O4 ], K[LiSO 4 ], Na[AlSiO 4 ] (Nephelin)und SisO* (0-Tridymit), Naturwissenschaften30, 471-472 (1942).43
Page 1 and 2: c ^r.
Page 3 and 4: UNITED STATES DEPARTMENT OF COMMERC
Page 5 and 6: Introduction.. _ __________________
Page 7 and 8: STANDARD X-RAY DIFFRACTION POWDER P
Page 9 and 10: D. E. Appleman, and D. Handworker.
Page 11 and 12: Ammonium Fluoberyllate, (NH4) 2BeF4
Page 13 and 14: Ammonium Fluoborate, NH4BF4 (orthor
Page 15 and 16: Arsenic Trioxide, claudetite, As2O3
Page 17 and 18: Powder data cardsBarium Stannate, B
Page 19 and 20: Bismuth Orthophosphate, BiPO4 (trig
Page 21 and 22: Bismuth Orthovanadate (high form),
Page 23 and 24: Bismuth Telluride (tellurobismuthit
Page 25 and 26: Cadmium Perchlorate Hexahydrate, Cd
Page 27 and 28: Cadmium Telluride, CdTe (cubic)Powd
Page 29 and 30: Calcium Fluoride Phosphate (fluorap
Page 31 and 32: Cesium Chromate, Cs>CrO 4 (orthorho
Page 33 and 34: Cobalt Fluosilkate Hexahydrate, CoS
Page 35 and 36: Copper Sulfate (chalcocyanite), CuS
Page 37 and 38: Erbium Arsenate, ErAsO4 (tetragonal
Page 39 and 40: Gallium Arsenide, GaAs (cubic)Powde
Page 41 and 42: Indium Arsenide, InAs (cubic)Powder
Page 43 and 44: Lanthanum Niobium Titanium Oxide, L
Page 45 and 46: Lithium Phosphate, high form, Li3PO
Page 47: Magnesium Ammonium Phosphate Hexahy
Page 51 and 52: Potassium Zinc Decavanadate 16 Hydr
Page 53 and 54: Silver Antimony Telluride, AgSbTe2
Page 55 and 56: Sodium Trimetaphosphate, Na3P3O9 (o
Page 57 and 58: Sodium Trimetaphosphate Monohydrate
Page 59 and 60: Strontium 1:1 Berate, SrO-B2O3 (ort
Page 61 and 62: Thallium Chromate, Tl2CrO4 (orthorh
Page 63 and 64: Titanium Dioxide, brookite, TiO2 (o
Page 65 and 66: CUMULATIVE INDEX TO CIRCULAR 539, V

Standard X-ray Diffraction Powder Patterns

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