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Bush__The_Essential_Physics_for_Medical_Imaging - Biomedical ...

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<strong>The</strong> probability of photoelectric absorption per unit mass is approximately proportionalto Z3/E3, where Z is the atomic number and E is the energy of the incidentphoton. For example, the photoelectric interaction probability in iodine (Z =53) is (53/20)3 or 18.6 times greater than in calcium (Z = 20) <strong>for</strong> photon of a particularenergy.<strong>The</strong> benefit of photoelectric absorption in x-ray transmission imaging is thatthere are no additional nonprimary photons to degrade the image. <strong>The</strong> fact that theprobability of photoelectric interaction is proportional to 1/E3 explains, in part,why image contrast decreases when higher x-ray energies are used in the imagingprocess (see Chapter 10). If the photon energies are doubled, the probability of photoelectricinteraction is decreased eightfold: ('/2)3 = 1/8.Although the probability of the photoelectric effect decreases, in general, withincreasing photon energy, there is an exception. For every element, a graph of theprobability of the photoelectric effect, as a function of photon energy, exhibits sharpdiscontinuities called absorption edges (see Fig. 3-11). <strong>The</strong> probability of interaction<strong>for</strong> photons of energy just above an absorption edge is much greater than thatof photons of energy slightly below the edge. For example, a 33.2-keV x-ray photonis about six times as likely to have a photoelectric interaction with an iodineatom as a 33.1-keV photon.AB mentioned above, a photon cannot undergo a photoelectric interaction withan electron in a particular atomic shell or subshell if the photon's energy is less thanthe binding energy of that shell or subshell. This causes the dramatic decrease in theprobability of photoelectric absorption <strong>for</strong> photons whose energies are just belowthe binding energy of a shell. Thus, the photon energy corresponding to an absorptionedge is the binding energy of the electrons in that particular shell or subshell.An absorption edge is designated by a letter, representing the atomic shell of theelectrons, followed by a number denoting the subshell (e.g., K, L1, L2, L3, etc.).<strong>The</strong> photon energy corresponding to a particular absorption edge increases with theatomic number (Z) of the element. For example, the primary elements comprisingsoft tissue (H, C, N, and 0) have absorption edges below 1 keY: <strong>The</strong> elementsiodine (Z = 53) and barium (Z = 56), commonly used in radiographic contrastagents to provide enhanced x-ray attenuation, have K-absorption edges of 33.2 and37.4 keV respectively (Fig. 3-10). <strong>The</strong> Kedge energy of lead (Z = 82) is 88 keY:At photon energies below 50 keV the photoelectric effect plays an importantrole in imaging soft tissue. <strong>The</strong> photoelectric absorption process can be used to

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