Shodex Catalogue 2013-2015.pdf - Analytics Shop
Shodex Catalogue 2013-2015.pdf - Analytics Shop
Shodex Catalogue 2013-2015.pdf - Analytics Shop
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Standard cations (YS-50 and YK-421)1234YS-5010μL inj.56Sample :1. Li + 2mg/L2. Na + 10mg/L3. NH + 4 10mg/L4. K + 20mg/L5. Mg 2+ 10mg/L6. Ca 2+ 20mg/LYK-421213415μL inj.65YS-50 is a high performance typecolumn offers twice increasedtheoretical plate number than YK-421does. In particular, the peak shape isimproved. The quantitative performancefor NH 4+ in a sample containing highconcentration Na + is also enhanced.Resolutionfactor ofNa + and NH 4+YS-502.5YK-4212.1Standard AnalysisColumns018-Crown 6-ether conc.6mM3mM1mM0mM5 10 15 20 min 0 5 10 15 20 minColumn : <strong>Shodex</strong> IC YS-50Eluent : 4mM Methanesulfonic acid aq.Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 40˚CEffects of crown ether in eluentCrown ether forms complex with cations. The elution ofcations (particularly K + ) can be well controlled by thedifference in complex formation rate.1221 321 33213444545556666Sample : 10μL1. Li + 2mg/L2. Na + 10mg/L3. NH + 4 10mg/L4. K + 20mg/L5. Mg 2+ 10mg/L6. Ca 2+ 20mg/L1 234560 5 10 15 20 25 30 35minTPMg 2+Ca 2+Column : <strong>Shodex</strong> IC YK-421Eluent : 5mM Tartaric acid + 1mM Dipicolinic acid + 1.5g/L Boric acid aq.Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 40˚CYS-507YK-4216,900 3,0006,600 3,000Simultaneous analysis for cations and ethylenediamineSample : 10μL1. Li + 2mg/L2. Na + 10mg/L3. NH + 4 10mg/L4. K + 20mg/L5. Mg 2+ 10mg/L6. Ca 2+ 20mg/L7. Ethylenediamine 50mg/LColumns for Ion Chromatography (Cation Analysis)05 10 15 20 minColumn : <strong>Shodex</strong> IC YS-50Eluent : 4mM Methanesulfonic acid + 18-Crown 6-ether aq.Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 40˚CColumn : <strong>Shodex</strong> IC YS-50Eluent : 4mM Nitric acid + 1.5mM 18-Crown 6-ether aq./CH 3 CN=90/10Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 40˚CAlkylaminesAlkaline earth metal ions1Sample : 50μL1. NH + 4 5mg/L2. Methylamine 5mg/L3. Dimethylamine 5mg/L4. Trimethylamine 20mg/L5. Ethylamine 10mg/L6. Propylamine 10mg/L7. Butylamine 10mg/Lmin2Cu 2+Zn 2+Ni 2+Co 2+3Mg 2+Fe 2+ , Fe 3+Mn 2+ , Pb 3+Cd 2+4Ca 2+13Sample : 10μL1. Ni 2+ 50mg/L2. Mg 2+ 20mg/L3. Mn 2+ 50mg/L4. Ca 2+ 50mg/L42345Sr 2+2256767Ba 2+0 1 2 3 4 5 min05 10 minColumn : <strong>Shodex</strong> IC YK-421Eluent : 4mM H 3 PO 4 aq./CH 3 CN=90/10Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 25˚C8Column : <strong>Shodex</strong> IC Y-521Eluent : 4mM Tartaric acid + 2mM Ethylenediamine aq.Flow rate : 1.0mL/minDetector : Non-suppressed conductivityColumn temp. : 40˚C25