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Air Quality Guidelines Global Update 2005 - World Health ...

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SOURCES OF AIR POLLUTION<br />

in diameter (1 nm = 10 –9 m), while coarse dust and sea salt particles can be as<br />

large as 100 μm (1 μm = 10 –6 m) or 0.1 mm in diameter. However, the very large<br />

particles have a short atmospheric existence, tending to fall out rapidly through<br />

gravity and wind-driven impaction processes. Thus in practice there are few particles<br />

in the atmosphere exceeding 20 μm in diameter, except in areas very close<br />

to sources of emission. Particulate matter can be separated from atmospheric<br />

gases by drawing air through a filter fine enough to retain the particles, or by<br />

accelerating air through a jet that fires them at a fixed plate, onto which the particles<br />

impact and are collected. Particulate air pollutants have very diverse chemical<br />

compositions that are highly dependent on their source. They are also diverse<br />

in terms of particle size. Fig. 1 illustrates the range of sizes (on a logarithmic<br />

scale) together with the ranges where certain important components are typically<br />

encountered. It shows also the PM10, PM2.5 and ultrafine particle fractions, which<br />

are typically those measured within the atmosphere for the purposes of health effects<br />

studies; the first two fractions are also used for compliance monitoring.<br />

Fig. 1. Size range of airborne particles, showing the health-related ultrafine, PM2.5 and<br />

PM10 fractions and the typical size range of some major components<br />

Ultrafine fraction<br />

Diesel smoke<br />

PM2.5<br />

Sulfate<br />

PM10<br />

Nitrate<br />

Soil, road dust<br />

PM2.5−10<br />

0.001 0.01 0.1 1.0<br />

Particle diameter (μm)<br />

10 100<br />

In the context of discussing sources of air pollution, it is important to consider<br />

the geographical location and distribution of sources. <strong>Air</strong> pollution occurs on a<br />

range of spatial scales linked primarily to the atmospheric lifetime of the specific<br />

pollutants. Typical spatial scales are the following.<br />

Local scale<br />

Some pollutants, by virtue of their source or of having a very short atmospheric<br />

lifetime, are only encountered in appreciable concentrations close to where<br />

they are emitted. Examples are mainly rather esoteric chemicals, emitted from<br />

11

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