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xx CONTENTS<br />

3 Transport <strong>Upscaling</strong> Using Multi-Rate <strong>Mass</strong> Transfer in Three-<br />

Dimensional Highly Heterogeneous Media (published in Advances in<br />

Water Resources) 43<br />

3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44<br />

3.2 Methodology . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46<br />

3.2.1 Background . . . . . . . . . . . . . . . . . . . . . . . . . 46<br />

3.2.2 Hydraulic conductivity upscaling using the Laplacianwith-skin<br />

method . . . . . . . . . . . . . . . . . . . . . . 49<br />

3.2.3 Transport upscaling using mass transfer . . . . . . . . . 51<br />

3.3 Numerical Evaluation . . . . . . . . . . . . . . . . . . . . . . . 53<br />

3.3.1 Model Configuration . . . . . . . . . . . . . . . . . . . . 53<br />

3.3.2 <strong>Flow</strong> upscaling results . . . . . . . . . . . . . . . . . . . 56<br />

3.3.3 Transport upscaling results . . . . . . . . . . . . . . . . 58<br />

3.3.4 Propagation <strong>of</strong> Uncertainty . . . . . . . . . . . . . . . . 62<br />

3.4 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64<br />

3.5 Summary <strong>and</strong> Conclusions . . . . . . . . . . . . . . . . . . . . . 67<br />

Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69<br />

4 <strong>Modeling</strong> Transient <strong>Groundwater</strong> <strong>Flow</strong> by Coupling Ensemble<br />

Kalman Filtering <strong>and</strong> <strong>Upscaling</strong> (submitted to Water Resources<br />

Research) 75<br />

4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76<br />

4.2 Methodology . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78<br />

4.2.1 Generation <strong>of</strong> the Ensemble <strong>of</strong> Fine Scale Conductivities 78<br />

4.2.2 <strong>Upscaling</strong> . . . . . . . . . . . . . . . . . . . . . . . . . . 78<br />

4.2.3 The EnKF with Hydraulic Conductivity Tensors . . . . 80<br />

4.3 Application Example . . . . . . . . . . . . . . . . . . . . . . . . 83<br />

4.3.1 Reference Field . . . . . . . . . . . . . . . . . . . . . . . 83<br />

4.3.2 Hydraulic Conductivity <strong>Upscaling</strong> . . . . . . . . . . . . 84<br />

4.3.3 Case Studies . . . . . . . . . . . . . . . . . . . . . . . . 86<br />

4.3.4 Performance Measurements . . . . . . . . . . . . . . . . 88<br />

4.4 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89<br />

4.4.1 The EnKF Coupled with <strong>Upscaling</strong> . . . . . . . . . . . . 90<br />

4.4.2 Worth <strong>of</strong> Data . . . . . . . . . . . . . . . . . . . . . . . 96<br />

4.4.3 Other Issues . . . . . . . . . . . . . . . . . . . . . . . . . 99<br />

4.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100<br />

Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101<br />

5 Jointly Mapping Hydraulic Conductivity <strong>and</strong> Porosity by Assimilating<br />

Concentration Data via Ensemble Kalman Filter<br />

(submitted to Journal <strong>of</strong> Hydrology) 105<br />

5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106

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