Capítulo 8 bands have been measured for different axial positions along the <strong>plasma</strong> flame. The lateral distributions of emission intensity of the excited species for each axial position were obtained by calculating the area <strong>un</strong><strong>de</strong>r each spectral profile at each lateral position. Following Abel inversion, such distributions provi<strong>de</strong>d the radial distributions of the emissivity for the different studied excited species: Cl I, Cl II, Cl III, Cu I, CuCl, N2 + , CO2, C2, CN, O I and N I. The data in figure 8.1 show that in the area where the temperature is higher, near the tip, chlorine is ionized and carbon bands are observed as a result of the <strong>de</strong>struction of CCl4. A little higher, chlorine reacts with copper booted from the tip to form CuCl. Copper booted from the tip can be seen only in areas higher than 20 mm, because in areas below reacts with chlorine. The atmospheric gases such as nitrogen, oxygen and CO2 are excited in the upper and external zone of the <strong>plasma</strong> flame, where it is col<strong>de</strong>r and there are entry surro<strong>un</strong>ding gases. The source of CO2 is also due to the reaction of products of the <strong>de</strong>struction with atmospheric gases. 177
Axial position (mm) Axial Position (mm) Axial Position (mm) Distribución <strong>de</strong> temperaturas y especies 40 35 30 25 20 15 10 5 Cl I -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) 40 35 30 25 20 15 10 80 70 60 50 40 30 20 10 5 Cu I Figure 8.1: Axial and radial distribution of the excited species produced in the helium <strong>plasma</strong> during the <strong>de</strong>struction of CCl 4. Figures from a to g and i correspond to excited species from <strong>de</strong>struction of CCl 4 and subsequent recombinations. In the figures d and e appear copper as an element introduced into the <strong>plasma</strong> by erosion of the tip of the torch. Figures h, j and k show excitement of the elements of the surro<strong>un</strong>ding air outsi<strong>de</strong> the <strong>plasma</strong>. The gradation of colors corresponds to the intensity of the lines in arbitrary <strong>un</strong>its. The wavelengths and the molecular transitions of the lines and the rotational bands used in of each figure are: a) Cl I (754.7 nm), b) Cl II (479.4 nm), c) Cl III (374.9 nm), d) Cu I (296.1 nm), e) CuCl 1 ∑→ 1 ∑ system E (433.3 nm), f) C 2 A 3 ∏ g →X 3 ∏ u Swan system (467.9 nm), g) CN B 2 ∑→A 2 ∏ cyanogen violet system (388.3 nm), h) N 2 + B 2 ∑ + u→X 2 ∑ + g first negative system (391.4 nm), i) CO 2 Fox system (337.7 nm), j) O I (844.6 nm), k) N I (746.8 nm). 178 a) I (a.u.) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) CO 2 0 137,5 275,0 412,5 550,0 687,5 825,0 962,5 1100 1238 1375 1513 1650 1788 1925 2063 2200 d) I (a.u.) Axial Position (mm) 40 35 30 25 20 15 10 5 CN 0 75,00 150,0 225,0 300,0 375,0 450,0 525,0 600,0 675,0 750,0 825,0 900,0 975,0 1050 1125 1200 Axial Position (mm) Axial Position (mm) 40 35 30 25 20 15 10 40 35 30 25 20 15 10 5 5 Cl II b) I (a.u.) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) CuCl -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) i) I (a.u.) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) 0 112,5 225,0 337,5 450,0 562,5 675,0 787,5 900,0 40 1013 1125 30 1238 1350 1463 20 1575 1688 1800 0 112,5 225,0 337,5 450,0 562,5 675,0 787,5 900,0 1013 1125 1238 1350 1463 1575 1688 1800 e) I (a.u.) 0 588,2 1176 1765 2353 2941 3529 4118 4706 5294 5882 6471 7059 7647 8235 8824 9412 10000 -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) g) I (a.u.) 0 75,00 150,0 40 35 N 225,0 300,0 375,0 30 450,0 525,0 25 600,0 675,0 20 750,0 825,0 900,0 15 975,0 1050 10 1125 1200 5 + 2 Axial Position (mm) 80 70 60 50 10 O I Axial Position (mm) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) Axial Position (mm) Axial Position (mm) 40 35 30 25 20 15 10 5 40 35 30 25 20 15 10 Cl III c) I (a.u.) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) 5 C 2 -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) j) I (a.u.) 0 87,50 175,0 262,5 350,0 437,5 525,0 612,5 700,0 787,5 875,0 962,5 1050 1138 1225 1313 1400 Axial Position (mm) f) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) h) I (a.u.) 80 70 60 50 40 30 20 10 N I 0 112,5 225,0 337,5 450,0 562,5 675,0 787,5 900,0 1013 1125 1238 1350 1463 1575 1688 1800 0 56,25 112,5 168,8 225,0 281,3 337,5 393,8 450,0 506,3 562,5 618,8 675,0 731,3 787,5 843,8 900,0 I (a.u.) -1,5 -1,0 -0,5 0,0 0,5 1,0 1,5 Radial Position (mm) 0 75,00 150,0 225,0 300,0 375,0 450,0 525,0 600,0 675,0 750,0 825,0 900,0 975,0 1050 1125 1200 k) I (a.u.) 0 87,50 175,0 262,5 350,0 437,5 525,0 612,5 700,0 787,5 875,0 962,5 1050 1138 1225 1313 1400
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UNIVERSIDAD DE CÓRDOBA FACULTAD DE
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ESTUDIO Y CARACTERIZACIÓN DE UN PL
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Este trabajo ha sido realizado en e
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Dedicado a Rocío, Darío y Noah Un
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Índice DESTRUCCIÓN DE VOCS CON PL
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Índice iv 4.4. Ejemplo: Antorcha d
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ÍNDICE DE FIGURAS Figura I.1: Esqu
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Índice Figure 3.11: Variation of t
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Índice Figure 6.5: Radial and axia
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ESTRUCTURA Y OBJETIVOS El presente
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I.1. Compuestos orgánicos volátil
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Introducción droguerías. En el si
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Introducción agua subterránea. Es
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I.2.1. Técnicas de recuperación d
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Introducción concentraciones relat
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Introducción cuando el gas sale de
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Introducción los gases a algún va
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Introducción incineradores catalí
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Introducción En la figura I.3 se m
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Introducción plasma, y por tanto r
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I.3.1. Descargas corona pulsadas In
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Introducción En este caso, la mues
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Introducción por tanto, las dimens
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Introducción refiere. De hecho la
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Introducción [26] Hsiao MC, Merrit
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CAPÍTULO 1 REMOVAL OF VOLATILE ORG
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1.2. Experimental set-up Capítulo
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Capítulo 1 The destruction percent
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Capítulo 1 Our data also support t
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% DRE % DRE 100,0000 100,0000 99,99
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Capítulo 1 Energy efficiencies of
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CAPÍTULO 2 APPLICATION OF A MICROW
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Capítulo 2 at atmospheric pressure
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2.2.1. Microwave generator and coup
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2.3. Results 2.3.1. Destruction of
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Capítulo 2 mm. The curves are simi
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Capítulo 2 In obtaining high energ
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Capítulo 2 Figure 2.6b shows the v
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Capítulo 2 revealed the presence o
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Capítulo 2 destruction step but un
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Capítulo 2 concentrations in the p
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[23] B.M. Penetrante, et al.: Plasm
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CAPÍTULO 3 ASSESSMENT OF A NEW CAR
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Capítulo 3 enhanced destruction an
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3.2.1. Microwave generator and its
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3.2.2. Sample insertion Capítulo 3
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Capítulo 3 concentration was a res
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Capítulo 3 Figure 3.4: Variation o
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Capítulo 3 different microwave pow
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Concentration CO 2 (ppm) 10000 1000
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Capítulo 3 CuCl2·2H2O on glass su
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Capítulo 3 Figure 3.10 shows some
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3.4. Conclusions Capítulo 3 The pr
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Capítulo 3 [14] A. Rodero, M.C. Qu
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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Destrucción de VOCs con plasma de
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CAPÍTULO 5 APPLICATION OF MICROWAV
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Capítulo 5 99% were achieved. Usin
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COMPONENT DESCRIPTION Microwave gen
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