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estudio y caracterización de un plasma de microondas a presión ...

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Capítulo 2<br />

In obtaining high energy efficiency with the trichloroethylene <strong>de</strong>struction<br />

method, used in this work, entails removing a large amo<strong>un</strong>t of contaminant per <strong>un</strong>it time<br />

by using as little energy as possible. Such efficiency can be increased simply by<br />

increasing the flow-rate of input gas and the inner diameter of the nozzle, while keeping<br />

the velocity within the optimum range.<br />

Figure 2.5 shows the energy efficiency of the helium <strong>plasma</strong> as a f<strong>un</strong>ction of the<br />

inner diameter of the coupler tip at five different C2HCl3 concentrations. As can be seen,<br />

the larger the inner diameter of the tip, the higher the energy efficiency at a constant<br />

output velocity of gas. This testifies to the high flexibility of the system, which allows<br />

the energy efficiency to be increased by altering the dimensions of the coupler tip,<br />

simply replacing with a new one.<br />

The data shown in figure 2.5 maintain a constant velocity of the gas at its<br />

optimum value, which for an internal diameter of 1.4 mm corresponds to approximately<br />

3 L/min, but greater energy efficiency can be achieved by increasing the gas flow,<br />

though this causes a reduction in the <strong>de</strong>struction efficiency.<br />

2.3.1.4. Influence of the contaminant concentration<br />

Figure 2.6a shows the variation of the output concentration of C2HCl3 as a<br />

f<strong>un</strong>ction of that introduced in the helium <strong>plasma</strong> at six different applied microwave<br />

power values from 100 to 1000 W. For values of power less than 300 W it is not possible<br />

to use a high concentrations of C2HCl3 in the inlet gas because the <strong>plasma</strong> is <strong>un</strong>stable. As<br />

can be seen, below 300 W the output concentration increases with an increased input<br />

concentration; no such effect is observed above 300 W because the output concentration<br />

is already very low.<br />

In any case, the increase in concentration at the reactor outlet is not an accurate<br />

measure of the <strong>de</strong>structive ability of the <strong>plasma</strong> since this is receiving an increased<br />

amo<strong>un</strong>t of product per <strong>un</strong>it time. It is therefore preferable to use an alternative<br />

parameter: the <strong>de</strong>struction and removal efficiency, %DRE [21].<br />

57

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