estudio y caracterización de un plasma de microondas a presión ...
estudio y caracterización de un plasma de microondas a presión ...
estudio y caracterización de un plasma de microondas a presión ...
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Destrucción <strong>de</strong> VOCs con <strong>plasma</strong> <strong>de</strong> Helio<br />
64<br />
Intensity (a.u.)<br />
10000<br />
9000<br />
8000<br />
7000<br />
6000<br />
5000<br />
4000<br />
3000<br />
2000<br />
1000<br />
2.4. Conclusions<br />
0<br />
468 469 470 471 472 473 474 475<br />
Figure 2.13: Rotational bands of C 2 in the discharge.<br />
The proposed <strong>plasma</strong> system for <strong>de</strong>stroying volatile organic residues is effective<br />
in respect of <strong>de</strong>composing trichloroethylene. Its <strong>de</strong>struction efficiency increases with<br />
increasing applied microwave power, but the achieved percentage of <strong>de</strong>struction is<br />
99.99% at 300 W. An optimum flow-rate range exists at each diameter of the coupler tip<br />
that corresponds to a gas velocity of ca. 35 m/s. This, together with the ability to replace<br />
the tip with another one of a larger diameter, allows the efficiency of the process to be<br />
raised to levels up to 600 g/kW·h.<br />
Cu I<br />
C 2 Rotational Bands<br />
Helium <strong>plasma</strong><br />
Flow rate: 1 L/min<br />
MW power: 600 W<br />
1000 ppmv C 2 HCl 3<br />
Wavelength (nm)<br />
Consistent with previous results, the percentage of <strong>de</strong>struction of the proposed<br />
system increases with an increased input concentration of C2HCl3,<br />
The analysis of by-products of the process revealed that the output concentration<br />
of C2HCl3 upon treatment in the <strong>plasma</strong> falls in the ppbv range <strong>un</strong><strong>de</strong>r optimal conditions<br />
and that the treatment generates two other volatiles (ClCl4 and C2Cl4), both at a