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estudio y caracterización de un plasma de microondas a presión ...

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Destrucción <strong>de</strong> VOCs con <strong>plasma</strong> <strong>de</strong> Helio<br />

64<br />

Intensity (a.u.)<br />

10000<br />

9000<br />

8000<br />

7000<br />

6000<br />

5000<br />

4000<br />

3000<br />

2000<br />

1000<br />

2.4. Conclusions<br />

0<br />

468 469 470 471 472 473 474 475<br />

Figure 2.13: Rotational bands of C 2 in the discharge.<br />

The proposed <strong>plasma</strong> system for <strong>de</strong>stroying volatile organic residues is effective<br />

in respect of <strong>de</strong>composing trichloroethylene. Its <strong>de</strong>struction efficiency increases with<br />

increasing applied microwave power, but the achieved percentage of <strong>de</strong>struction is<br />

99.99% at 300 W. An optimum flow-rate range exists at each diameter of the coupler tip<br />

that corresponds to a gas velocity of ca. 35 m/s. This, together with the ability to replace<br />

the tip with another one of a larger diameter, allows the efficiency of the process to be<br />

raised to levels up to 600 g/kW·h.<br />

Cu I<br />

C 2 Rotational Bands<br />

Helium <strong>plasma</strong><br />

Flow rate: 1 L/min<br />

MW power: 600 W<br />

1000 ppmv C 2 HCl 3<br />

Wavelength (nm)<br />

Consistent with previous results, the percentage of <strong>de</strong>struction of the proposed<br />

system increases with an increased input concentration of C2HCl3,<br />

The analysis of by-products of the process revealed that the output concentration<br />

of C2HCl3 upon treatment in the <strong>plasma</strong> falls in the ppbv range <strong>un</strong><strong>de</strong>r optimal conditions<br />

and that the treatment generates two other volatiles (ClCl4 and C2Cl4), both at a

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