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Capítulo 1<br />

Energy efficiencies of more than 500 g/kWh were achieved in our apparatus with<br />

<strong>de</strong>struction and removal efficiencies up to 99.999%.<br />

Hence, it is important to state that the results presented previously in figs. 1.2-1.6<br />

were obtained on a laboratory scale with a tip that had the smallest diameter. However,<br />

in an industrial processing facility, it would be more appropriate to use bigger cross-<br />

sections.<br />

1.5. Conclusions<br />

This paper reports the effects of microwave power, gas flow rate, and TCE<br />

concentration on the <strong>de</strong>composition efficiency of TCE by a microwave torch. The<br />

following observations are noteworthy:<br />

- The TIA seems to be a promising <strong>de</strong>vice for VOC <strong>de</strong>struction yielding high<br />

percentage <strong>de</strong>struction efficiencies at comparatively low power expenditure.<br />

- The TCE <strong>de</strong>composition increases with microwave power.<br />

- At fixed TCE concentrations and applied microwave powers, the <strong>de</strong>composition<br />

efficiency <strong>de</strong>creases as the gas flow increases.<br />

- The <strong>de</strong>composition efficiency was slightly higher with higher TCE<br />

concentrations, which implies that more TCE molecules are <strong>de</strong>composed for a given<br />

amo<strong>un</strong>t of energy when the TCE concentration is higher. This suggests that secondary<br />

<strong>de</strong>composition processes of TCE can be induced by fragment ions and radicals resulting<br />

from the initial <strong>de</strong>composition of TCE [9, 10].<br />

- Energy efficiencies up to 500 g/kWh can be achieved using tips of the torch<br />

with higher cross-sections of the tip of the torch. The <strong>de</strong>struction efficiency <strong>de</strong>pends on<br />

the velocity of the gas in the exit of the tip so that a larger quantity of TCE can be<br />

<strong>de</strong>stroyed per minute when tips with higher cross-sections are used.<br />

- The performance of the TIA can be optimised for a wi<strong>de</strong> range of TCE<br />

concentrations.<br />

45

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