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Dossier<br />

102496<br />

46<br />

SolvayInnovationTrophy2006<br />

SILANE: A COMPETITIVE ALTERNATIVE TO HIGH-<br />

PRESSURE STEAM CROSSLINKING TECHNOLOGY<br />

KNOW-HOW KEEPING<br />

THE COMPETITION AT BAY<br />

The cable market demands high levels<br />

of productivity yet low energy and<br />

investment costs. This project sets out to<br />

study and produce new families of material<br />

based on composite polymers to be used as<br />

insulator and sheathing for electrical cables<br />

(certain grades of which must resist fire,<br />

without recourse to halogens, nitrogen<br />

or phosphorus). But the main objective was<br />

to achieve performances only made possible<br />

by high-pressure steam drying reticulation<br />

(vulcanization) technology: softness and<br />

flexibility, elastic recover, resistance to fluids<br />

and to temperature.<br />

By studying the new polymer systems and<br />

production technologies using the Sioplassilane<br />

crosslinking technology, these<br />

properties are now available for products<br />

obtained from the classical thermoplastic<br />

extrusion lines, with a string of side benefits :<br />

low cost energy and maintenance, low<br />

investment cost for the extrusion,<br />

productivity multiplied by four, high degree<br />

of flexibility of production and waste<br />

reduction. The project, which got off the<br />

ground in 2004, has already spawned a new<br />

generation of products that are used in a<br />

number of special applications and that are<br />

quickly developing in terms of sales volumes.<br />

For the time being, no other manufacturer<br />

is selling these compounds, as our<br />

technological know-how is the best barrier<br />

to competition and an excellent way to gain<br />

customers’ loyalty.<br />

> Antonello Casale; Caterina Bocchia.<br />

> SBU SPECIALTY POLYMERS<br />

104040<br />

DYDROGESTERONE NEW PROCESS<br />

PURITY AND PERFORMANCE<br />

INCREASED<br />

Dydrogesterone is produced using<br />

“proketal”, with “retroketal”<br />

as an intermediary product. The new process,<br />

which follows the same sequence,<br />

has introduced additional “retroketal”<br />

crystallisation stages, making it much more<br />

pure. The yield of the last stage, during<br />

which the “retroketal” is transformed<br />

into dydrogesterone, has been substantially<br />

improved. Designed by Solvay<br />

Pharmaceuticals, the new unit, built<br />

in cooperation with Jacobs Engineering,<br />

was started up in two successive phases,<br />

during the 3rd and 4th quarters of 2004.<br />

It offers the following advantages:<br />

• reduction in the costs of the materials<br />

• the pooling on single line of the hygiene<br />

and environmental aspects and compliance<br />

with the GMP regulations.<br />

To sum up, Solvay Pharmaceuticals is very<br />

proud to present this new installation,<br />

internally, but also to external clients, such<br />

as pharmacists.<br />

> Ron Henneman; Fons Jacobs;<br />

Evert-Jan Jansen Schoonhoven.<br />

> PHARMACEUTICALS SECTOR<br />

104293<br />

CHECKING THE LOW IODINE DIET<br />

OF THE ELECTROLYSIS MEMBRANES<br />

OZONE TO THE<br />

MEMBRANES RESCUE<br />

The Group’s electrolytic plants<br />

are switching from mercury technology<br />

to membrane technology. In some cases,<br />

the brine that is electrolysed contains iodine<br />

as an impurity, which accumulates on the<br />

membranes and affects their efficiency.<br />

This iodine needs to be eliminated in an<br />

intermediary stage. The challenge consisted<br />

of internally developing a method for<br />

analysing the residual iodine, on the line,<br />

as no commercial solution existed. The new<br />

process that has been developed uses ozone<br />

to quantitatively transform the iodine into<br />

iodate, which is in turn analysed by<br />

spectrophotometer: a continuous analyser<br />

was developed for this method.<br />

After validation, the new system will, first of<br />

all, be installed in Rosignano (Italy). It may<br />

then be transposed to the electrolytic plants<br />

of the Group that run on salt containing<br />

iodine as an impurity.<br />

> Koen Vermeiren; Neil Breton;<br />

Davide Mantione; Alessandra Pastacaldi.<br />

> CC ANALYTICAL TECHNOLOGIES

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